| 新型L-苯丙氨酸桥联双卟啉的合成与光谱表征 |
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| 引用本文： | 罗国添,陈治希,饶明益,薛 珺,滕莉丽.新型L-苯丙氨酸桥联双卟啉的合成与光谱表征[J].无机化学学报,2011,27(7):1265-1270. |
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| 作者姓名： | 罗国添 陈治希 饶明益 薛 珺 滕莉丽 |
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| 作者单位： | 1. 赣南师范学院化学与生命科学学院,赣州 341000;江西省有机药物化学重点实验室,赣州 341000
2. 赣南师范学院化学与生命科学学院,赣州,341000 |
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| 基金项目： | 国家自然科学基金(No.20761001); 江西省自然科学基金(No.0420005); 江西省教育厅科技基金(No.GJJ11588)资助项目 |
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| 摘 要： | 用L-苯丙氨酸和5-对-(4-溴丁氧基、己氧基、辛氧基)苯基]-10，15，20-三苯基卟啉合成3种新型L-苯丙氨酸桥联双卟啉，并通过质谱、1H核磁共振谱、元素分析、红外光谱、紫外光谱对其结构进行了表征。测试并研究了它们在4 000~400 cm-1范围内的傅里叶变换红外光谱,对主要谱带进行了经验归属。
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| 关 键 词： | L-苯丙氨酸 双卟啉 合成 表征 |
Synthesis and Spectral Characterization of L-phenylalanine Bridged Bis-porphyrins |
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| LUO Guo-Tian,CHEN Zhi-Xi,RAO Ming-Yi,XUE Jun and TENG Li-Li.Synthesis and Spectral Characterization of L-phenylalanine Bridged Bis-porphyrins[J].Chinese Journal of Inorganic Chemistry,2011,27(7):1265-1270. |
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| Authors: | LUO Guo-Tian CHEN Zhi-Xi RAO Ming-Yi XUE Jun and TENG Li-Li |
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| Institution: | LUO Guo-Tian*,1,2 CHEN Zhi-Xi1 RAO Ming-Yi1 XUE Jun1 TENG Li-Li1(1College of Chemistry and Life Science,Gannan Normal University,Ganzhou,Jiangxi 341000,China)(2Key Laboratory of Organ-Pharmaceutical Chemistry of Jiangxi Province,China) |
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| Abstract: | Three new L-phenylalanine bridged bis-porphyrins were designed and synthesized from L-phenylalanine and 5-p-(n-bromo-butoxy, n-bromo-hexyloxy, n-bromo-octyloxy)phenyl]-10,15,20-triphenyl porphyrin. Their struc-tures were characterized by FAB-MS, 1H NMR, FTIR, UV-Vis, Elemental analysis and chemical analysis. The FTIR spectra (4 000~400 cm-1) of the target compounds were measured and the major bands were empirically assigned. |
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| Keywords: | L-phenylalanine bis-porphyrins synthesis characterization |
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