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TiO2薄膜光催化氧化I-的研究
引用本文:崔玉民,单德杰,朱亦仁.TiO2薄膜光催化氧化I-的研究[J].无机化学学报,2001,17(3):401-406.
作者姓名:崔玉民  单德杰  朱亦仁
作者单位:崔玉民(阜阳师范学院化学系,阜阳 236032);单德杰(阜阳师范学院化学系,阜阳 236032);朱亦仁(阜阳师范学院化学系,阜阳 236032)
基金项目:安徽省教委自然科学基金资助项目(No.99j10162)。
摘    要:采用溶胶-凝胶法,在玻璃珠表面涂覆均匀透明的TiO

关 键 词:溶胶-凝胶法  碘化物  光催化剂  碘离子  薄膜  二氧化钛  光催化氧化  催化活性
收稿时间:1/8/2001 12:00:00 AM
修稿时间:2001年1月8日

Studies on Photocatalytic Oxidation of I- over TiO2 Thin Film
CUI Yu-Min,SHAN De-Jie and ZHU Yi-Ren.Studies on Photocatalytic Oxidation of I- over TiO2 Thin Film[J].Chinese Journal of Inorganic Chemistry,2001,17(3):401-406.
Authors:CUI Yu-Min  SHAN De-Jie and ZHU Yi-Ren
Institution:Department of Chemistry, Fuyang Teacher's College, Fuyang 236032,Department of Chemistry, Fuyang Teacher's College, Fuyang 236032 and Department of Chemistry, Fuyang Teacher's College, Fuyang 236032
Abstract:In this article, photocatalytic oxidation of I- in aqueous solution has been studied with a photocatalytic glass reactor.The using catalyst is made of the glass beads as the carrier, and on the surface of every bead an evenly transparent TiO2 thin film was covered by the sol-gel process.It has been observed that the yield of I2 formation is dependent on the crystal structure of the catalyst, the illumination time, the initial concentrations of I- and H+.The results show that the yield of I2 can reach 41.26% over anatase TiO2- coated film, with photocatalyst(4.0g) in the solution of KI(3L), I-] of 0.3mol· L-1, H+] of 3.0mol·L-1 and illumination time of 8h.
Keywords:sol-gel process  iodide  photocatalyst  titanium dioxide  photocatalytic oxidation
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