| CuO表面修饰锐钛矿TiO2纳米管阵列及其电化学嵌锂性能 |
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| 引用本文： | 姚宇涵,苑振涛,张雁南,于晓华,荣菊,孟堃,詹肇麟.CuO表面修饰锐钛矿TiO2纳米管阵列及其电化学嵌锂性能[J].无机化学学报,2018,34(4):662-668. |
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| 作者姓名： | 姚宇涵 苑振涛 张雁南 于晓华 荣菊 孟堃 詹肇麟 |
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| 作者单位： | 昆明理工大学固体废弃物资源化国家工程研究中心, 昆明 650093;昆明理工大学材料科学与工程学院, 昆明 650093,昆明理工大学材料科学与工程学院, 昆明 650093,昆明理工大学材料科学与工程学院, 昆明 650093,昆明理工大学固体废弃物资源化国家工程研究中心, 昆明 650093;昆明理工大学材料科学与工程学院, 昆明 650093,昆明理工大学材料科学与工程学院, 昆明 650093;中国科学院金属研究所, 沈阳 110016,昆明理工大学材料科学与工程学院, 昆明 650093,昆明理工大学材料科学与工程学院, 昆明 650093 |
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| 基金项目： | 国家自然科学基金（No.51601081，51665022）、昆明理工大学人培项目（No.KKSY201628022）和云南省教育厅项目（No.2016ZZX031）资助。 |
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| 摘 要： | 以(CH_2OH)_2、NH4F和HCl为电解液,纯Ti片、CuCl_2和Na NO3为主要原料,联用阳极氧化和水热法制备CuO表面修饰锐钛矿TiO_2纳米管阵列锂离子电池负极材料(CuO/TiO_2)。使用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、能谱仪(EDS)、X射线光电子能谱仪(XPS)和X射线衍射(XRD),研究样品的形貌特征、元素分布、价态和微观物相组成。利用电池充放电测试仪和电化学工作站,探讨材料的电化学嵌锂性能。结果表明,表面修饰后的锐钛矿TiO_2纳米管阵列外侧出现了大量绒毛状纳米CuO,单个绒毛结构的宽度约4 nm,长度约10 nm。在0.3C的电流密度下进行恒电流充放电测试,首次放电容量为550 m Ah·g~(-1),充电容量为490 m Ah·g~(-1)。50次循环后,可逆电流容量仍保持在320 m Ah·g~(-1),具有良好的循环稳定性和电化学特性。
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| 关 键 词： | 表面修饰 TiO2纳米管阵列 CuO 电化学性能 微观结构 |
| 收稿时间： | 2017/11/1 0:00:00 |
| 修稿时间： | 2018/1/9 0:00:00 |
Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO |
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| YAO Yu-Han,YUAN Zhen-Tao,ZHANG Yan-Nan,YU Xiao-Hu,RONG Ju,MENG Kun and ZHAN Zhao-Lin.Surface Modification and Electrochemical Lithium Storage Performance of TiO2-Anatase Nanotube Arrays with CuO[J].Chinese Journal of Inorganic Chemistry,2018,34(4):662-668. |
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| Authors: | YAO Yu-Han YUAN Zhen-Tao ZHANG Yan-Nan YU Xiao-Hu RONG Ju MENG Kun and ZHAN Zhao-Lin |
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| Institution: | National Engineering Research Center of Solid Waste Resource, Kunming University of Science and Technology, Kunming 650093, China;Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China,Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China,Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China,National Engineering Research Center of Solid Waste Resource, Kunming University of Science and Technology, Kunming 650093, China;Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China,Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China;Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China,Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China and Faculty of Materials Science & Engineering, Kunming University of Science and Technology, Kunming 650093, China |
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| Abstract: | Anodic oxidation and hydrothermal method were jointly used to prepare CuO/TiO2 negative material which was synthesized from ethylene glycol, ammonium fluoride, hydrochloric acid, cupric chloride and sodium nitrate. Morphology, element distribution, valence state, microcosmic phase composition of the samples were investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD). Furthermore, the electro-chemical lithium insertion properties of CuO/TiO2 were tested by the use of battery charge and discharge testing system and electrochemical workstation. The results show that there are particulates arrange the surface of the anatase TiO2 nanotube. The nanometer size was 4 nm×10 nm. The as prepared CuO/TiO2 displays plummy electric properties of initial discharge and charge capacities of 550 and 490 mAh·g-1 at the rate of 0.3C. respe-ctively. After 50 cycles the reserve capacities is 320 mAh·g-1. |
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| Keywords: | surface modification TiO2-anatase nanotube array CuO electrochemical performance microscopic structure |
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