| 基于二羟基萘二磺酸根的配合物Na3[Na5(dhns)2]·(phen)4·2H2O的合成、晶体结构和热稳定性 |
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| 引用本文： | 魏赞斌,解庆范,陈延民.基于二羟基萘二磺酸根的配合物Na3[Na5(dhns)2]·(phen)4·2H2O的合成、晶体结构和热稳定性[J].无机化学学报,2013,29(7):1414-1418. |
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| 作者姓名： | 魏赞斌 解庆范 陈延民 |
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| 作者单位： | 厦门大学化学与化工学院, 厦门 360005;泉州师范学院化学与生命科学学院, 泉州 362000;泉州师范学院化学与生命科学学院, 泉州 362000 |
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| 基金项目： | 福建省教育厅科技基金(No.JA08212)和福建省科技厅科技项目(No.2008F5053)资助项目。 |
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| 摘 要： | 2,7-二羟基萘-3,6-二磺酸二钠盐(Na2H2dhns)与邻菲罗啉在乙醇/水溶液中自组装得到一新的配合物Na3Na5(dhns)2]·(phen)4·2H2O(1),并用CHN元素分析、IR、TGA和X-射线单晶衍射分析进行了表征。晶体属正交晶系,Pna21空间群,a=2.829 85(12)nm,b=1.038 99(14)nm,c=2.259 23(13)nm,V=6.642 6(10)nm3,Z=4,Dc=1.573 g.cm-3,R1=0.050 6,wR2=0.124 0,S=1.05。
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| 关 键 词： | 超分子 晶体结构 自组装 萘二磺酸 |
| 收稿时间： | 9/9/2012 12:00:00 AM |
| 修稿时间： | 2/3/2013 12:00:00 AM |
Synthesis, Crystal Structure and Thermal Stability of Complex Na3[Na5(dhns)2]·(phen)4·2H2O with Bihydroxynaphthalenedisulfonate |
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| WEI Zan-Bin,XIE Qing-Fan and CHEN Yan-Min.Synthesis, Crystal Structure and Thermal Stability of Complex Na3[Na5(dhns)2]·(phen)4·2H2O with Bihydroxynaphthalenedisulfonate[J].Chinese Journal of Inorganic Chemistry,2013,29(7):1414-1418. |
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| Authors: | WEI Zan-Bin XIE Qing-Fan and CHEN Yan-Min |
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| Institution: | College of Chemistry & Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China;College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China;College of Chemistry & Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China |
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| Abstract: | A new complex, Na3Na5(dhns)2]·(phen)4·2H2O, was obtained from the self-assembly of disodium 2,7-dihydroxy-naphthalene-3,6-disulfonate (Na2H2dhns) and 1,10-phenanthroline (Phen) in a water-ethanol solution. The compound was characterized by elemental analysis, IR, TGA, and X-ray diffraction single crystal structure analyses. The compound crystallizes in the orthorhombic system, space group Pna21, a=2.829 85(12) nm, b=1.038 99(14) nm, c=2.259 23(13) nm, V=6.642 6(10) nm3, Z=4, Dc=1.573 g·cm-3, R1=0.050 6, wR2=0.124 0, S=1.05. CCDC: 881794. |
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| Keywords: | supramolecule crystal strucrure self-assembly naphthalenedisulfonic acid |
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