| 四面体型过渡金属配合物的构型与CD的关系 |
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| 引用本文： | 周志华,汤杰,胡秀贞.四面体型过渡金属配合物的构型与CD的关系[J].无机化学学报,1989,5(2):64-68. |
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| 作者姓名： | 周志华 汤杰 胡秀贞 |
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| 作者单位： | 南京师范大学 南京
(周志华，汤杰)，南京师范大学 南京(胡秀贞) |
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| 摘 要： | 旋光性四面体型过渡金属配合物的圆二色光谱(CD)在d-d跃迁区的特征谱线反映了该类配合物的构型特征。从极化度的多级圆球不对称性模型出发,可将这类配合物的构型与CD在d-d跃迁区的特征谱线之间建立起直接的联系。
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| 关 键 词： | 过渡金属配合物 圆二色光谱(CD) 构型 极化度 |
| 收稿时间： | 1987/9/17 0:00:00 |
RELATIONSHIP BETWEEN CONFIGURATION OF TETRAHEDRAL TRANSITION METAL COMPOUNDS AND CIRCULAR DICHROISM |
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| Zhou Zhihu,Tang Jie and Hu Xiuzhen.RELATIONSHIP BETWEEN CONFIGURATION OF TETRAHEDRAL TRANSITION METAL COMPOUNDS AND CIRCULAR DICHROISM[J].Chinese Journal of Inorganic Chemistry,1989,5(2):64-68. |
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| Authors: | Zhou Zhihu Tang Jie and Hu Xiuzhen |
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| Institution: | Department of Chemistry, Nangjing Normal University, Nanjing,Department of Chemistry, Nangjing Normal University, Nanjing and Department of Chemistry, Nangjing Normal University, Nanjing |
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| Abstract: | In this paper,we suggested that the characteristic spectra of the circular dichroism (CD) for optical active tetrahcdral transition metal coordination compounds in the d-d transition region reflect the configuration specificity of this type coordination compounds. From the unsymmetrical model of the multiple spheres of polarizability, we can establish the connection between the configuration of this type coordination compounds and characteristic spectra of CD in the d-d transition region. |
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| Keywords: | transition metal coordination compounds circular dichroism configuration polarizabllity |
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