| 配位聚合物[HgI2(btx)]n的制备、晶体结构及性能研究(btx=对二(1，2，4-三氮唑基甲基)苯) |
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| 引用本文： | 徐 虹,孟祥茹,韩华云,王 霞,侯红卫.配位聚合物[HgI2(btx)]n的制备、晶体结构及性能研究(btx=对二(1，2，4-三氮唑基甲基)苯)[J].无机化学学报,2004,20(9):1089-1092. |
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| 作者姓名： | 徐 虹 孟祥茹 韩华云 王 霞 侯红卫 |
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| 作者单位： | 郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052,郑州大学化学系，郑州 450052 |
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| 基金项目： | 河南省自然科学基金(No.004030500)，留学归国基金资助。 |
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| 摘 要： | A novel one-dimension coordination polymer HgI2(btx)]n was synthesized through the reaction of alpha, alpha’-dichloro-p-xylene and HgI2 in mixed MeOH-THF (1∶1) solution. The compound was characterized by X-ray crystallography and crystallizes in orthorhombic with space group Pnma. The cell parameters of the title compound are: a=0.936 3(2) nm, b=1.769 4(4) nm, c=1.032 2(2) nm, α=90°. Attractive I…I interactions link HgI2(btx) chains directly resulting in the formation of three-dimensional network structure. In addition, the compound shows better luminescence spectroscopic property in the solid state, and is thermally stable below 126 ℃. CCDC: 233053.
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| 关 键 词： | 配位聚合物 晶体结构 差热及热重分析 荧光性质 |
| 修稿时间： | 2004年3月2日 |
Synthesis, Crystal Structure and Properties of the Coordination Polymer [HgI2(btx)]n (btx=1-[4-(1H-1,2,4-triazol-1-ylmethyl)benzyl]-1H-1,2,4-triazole) |
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| XU Hong,MENG Xiang-Ru,HAN Hua-Yun,WANG Xia and HOU Hong-Wei.Synthesis, Crystal Structure and Properties of the Coordination Polymer [HgI2(btx)]n (btx=1-[4-(1H-1,2,4-triazol-1-ylmethyl)benzyl]-1H-1,2,4-triazole)[J].Chinese Journal of Inorganic Chemistry,2004,20(9):1089-1092. |
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| Authors: | XU Hong MENG Xiang-Ru HAN Hua-Yun WANG Xia and HOU Hong-Wei |
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| Institution: | Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052,Department of Chemistry, Zhengzhou University, Zhengzhou 450052 and Department of Chemistry, Zhengzhou University, Zhengzhou 450052 |
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| Abstract: | |
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| Keywords: | coordination polymer crystal structure thermal analysis luminescence spectroscopic property |
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