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| 二聚体[Ni(TSSB)(Phen)(H2O)]·4H2O的合成、表征、晶体结构及热分解研究 | |
| 引用本文： | 张淑华,蒋毅民,辛懋,周忠远.二聚体[Ni(TSSB)(Phen)(H2O)]·4H2O的合成、表征、晶体结构及热分解研究[J].无机化学学报,2005,21(9):1392-1396. |
| 作者姓名： | 张淑华 蒋毅民 辛懋 周忠远 |
| 作者单位： | 1. 桂林工学院材料与化学工程系,有色金属材料及其加工新技术教育部重点实验室,桂林,541004 2. 广西师范大学化学化工学院,桂林,541004 3. 香港理工大学应用生物与化学科学系,香港 |
| 基金项目： | 广西自然科学基金（No.0339034）和广西教育厅科研项目（No.[2004]20）资助. |
| 摘 要： | The new compound, Ni(TSSB)(Phen)(H2O)]·4H2O (TSSB=Taurine Salicylic Schiff Base, phen=O-Phenanthroline) has been synthesized and characterized by IR, elemental analysis and X-ray diffraction. The compound crystal data: triclinic, space group P1, a=1.049 7(2), b=1.122 5(2), c=2.384 3(4) nm, α=87.676(3)°, β=82.957(3)°, γ=62.924(3)°; V=2.482 3(7) nm3, Z=4; Dc=1.488 g·cm-3, μ=0.920 mm-1, F(000)=1 160, Goof=1.032, (Δρ)max=899 e·nm-3, (Δρ)min=-624 e·nm-3. The compound is a dimmer. In the complex, two Ni(Ⅱ) were coordinated by three oxygen atoms and three nitrogen atoms while the O atoms of Ac- groups did not coordinate. The Ni(Ⅱ) formed a distorted octahedron geometry. The compound is an three dimensional net connecting with hydrogen bonding. CCDC: 275474. |
| 关 键 词： | 镍(Ⅱ)配合物 牛磺酸缩水杨醛席夫碱 晶体结构 二聚体 |
| 文章编号： | 1001-4861(2005)09-1392-05 |
| 收稿时间： | 2004-10-10 |
| 修稿时间： | 6/2/2005 12:00:00 AM |
Synthesis, Characterization,Crystal Structure and Thermal Decomposition of the Dimmer Complex [Ni(TSSB)(Phen)(H2O)]·4H2O |
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| ZHANG Shu-Hu,JIANG Yi-Min,XING Mao and ZHOU Zhong-Yuan.Synthesis, Characterization,Crystal Structure and Thermal Decomposition of the Dimmer Complex [Ni(TSSB)(Phen)(H2O)]·4H2O[J].Chinese Journal of Inorganic Chemistry,2005,21(9):1392-1396. | |
| Authors: | ZHANG Shu-Hu JIANG Yi-Min XING Mao and ZHOU Zhong-Yuan |
| Institution: | Department of Material and Chemical Engineering, Guilin University of Technology, Key Laboratory of Non-ferrous Materials and New Processing Technology, Ministry of Education, Guilin 541004,School of Chemistry and Chemical Engineering , Guangxi Normal University, Guilin 541004,School of Chemistry and Chemical Engineering , Guangxi Normal University, Guilin 541004 and Department of Applied Biology and Chemical Technology, Hongkong Polytechnic University, Hongkong |
| Abstract: | |
| Keywords: | Nickel compound dimmer taurine-salicylaldehyde Schiff base crystal structure |
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