| 以氨基酸酯为轴向配体的铁、锰卟啉配合物的合成及表征 |
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| 引用本文： | 穆林静,邱晓航,周永洽,黄杰生,申泮文.以氨基酸酯为轴向配体的铁、锰卟啉配合物的合成及表征[J].无机化学学报,1997,13(3):344-346. |
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| 作者姓名： | 穆林静 邱晓航 周永洽 黄杰生 申泮文 |
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| 作者单位： | 南开大学化学系，天津 300071,南开大学化学系，天津 300071,南开大学化学系，天津 300071,南开大学化学系，天津 300071,南开大学化学系，天津 300071 |
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| 基金项目： | 天津市21世纪青年基金 |
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| 摘 要： | The new six-coordinate complexes (TPP)FeⅡ(Gly-OMe)2 C50H42FeN6O4 and (TPP)FeⅡ(β-Ala-OMe)2 (C52H46FeN6O4) wbere TPP=meso-tetraphenyl porphyrinate, Gly-OMe=glycine methyl ester, β-Ala-OMe=β-alanine methyl ester and five-coordinte complex (TPP)Mn(Ⅱ)(Gly-OMe) (C47H35MnN5O2) have been prepared by sodium borohydride method.These complexes were characterized by UV-Vis, IR, ESR, spectra and by elemental analysis. The synthesized divalent iron porphyrins are d6 low spin states and their UV-Vis spectra are Hypso type; while divalent manganese porphyrin is d5 high spin state and its UV-Vis spectrum is pseudo-Normal type.
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| 关 键 词： | 铁卟啉 锰卟啉 氨基酸酯 合成 表征 |
SYNTHESIS AND CHARACTERIZATION OF IRON AND MANGANESE PORPHYRIN COMPLEXES WITH AMINO-ACID-ESTERS AS AXIAL LIGAND |
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| Mu Linjing,Qiu Xiaohang,Zhou Yongqi,Huang Jiesheng and Shen Panwen.SYNTHESIS AND CHARACTERIZATION OF IRON AND MANGANESE PORPHYRIN COMPLEXES WITH AMINO-ACID-ESTERS AS AXIAL LIGAND[J].Chinese Journal of Inorganic Chemistry,1997,13(3):344-346. |
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| Authors: | Mu Linjing Qiu Xiaohang Zhou Yongqi Huang Jiesheng and Shen Panwen |
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| Institution: | Department of Chemistry, Nankai University, Tianjin, 300071,Department of Chemistry, Nankai University, Tianjin, 300071,Department of Chemistry, Nankai University, Tianjin, 300071,Department of Chemistry, Nankai University, Tianjin, 300071 and Department of Chemistry, Nankai University, Tianjin, 300071 |
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| Abstract: | |
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| Keywords: | iron porphyrin manganese porphyrin amino acid ester systhesis characterization |
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