| 穴状Schiff碱配合物［Gd(NO3)·L］(NO3)2的晶体结构 |
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| 引用本文： | 张明杰,马宁,聂玉敏,张文勤,孟庆朝.穴状Schiff碱配合物［Gd(NO3)·L］(NO3)2的晶体结构[J].无机化学学报,1997,13(3):355-357. |
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| 作者姓名： | 张明杰 马宁 聂玉敏 张文勤 孟庆朝 |
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| 作者单位： | 天津大学化学系，天津 300072,天津大学化学系，天津 300072,天津大学化学系，天津 300072,天津大学化学系，天津 300072,天津大学化学系，天津 300072 |
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| 基金项目： | 国家教育委员会留学回国人员基金 |
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| 摘 要： | A new mononuclear gadolinium complex ［Gd(NO3)·L］(NO3)2 of Schiff base cryptand was obtained by condensation of tris (2-aminoethyl)amine with 2,6-diformyl phenol in template procedure. The complex was characterized by elemental analysis, IR, and x-ray single crystal diffraction analysis. Gadolinium is nine-coordinate in trigonal tricapped prism with five oxygen atoms from three phenols and a bidentate nitrate group, and four nitrogen atoms from three imino C=N bonds and a tertiary amine in the cryptand. The complex crystallized in triclinic system space group P1, a=1.0839(2) nm, b=1.2600(4) nm, c=1.7595(4) nm, α=82.09(2)°, β=89.22(2)°, γ=84.06(2)°， V=2.367(2) nm3, Z=2.
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| 关 键 词： | 钆配合物 穴状Schiff碱 晶体结构 |
CRYSTAL STRUCTURE OF A MONONUCLEAR GADOLINIUM COMPLEX OF SCHIFF BASE CRYPTAND |
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| Zhang Mingjie,Ma Ning,Nie Yumin,Zhang Wenqin and Meng Qingzhao.CRYSTAL STRUCTURE OF A MONONUCLEAR GADOLINIUM COMPLEX OF SCHIFF BASE CRYPTAND[J].Chinese Journal of Inorganic Chemistry,1997,13(3):355-357. |
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| Authors: | Zhang Mingjie Ma Ning Nie Yumin Zhang Wenqin and Meng Qingzhao |
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| Institution: | Department of Chemistry, Tianjin University, Tianjin, 300072,Department of Chemistry, Tianjin University, Tianjin, 300072,Department of Chemistry, Tianjin University, Tianjin, 300072,Department of Chemistry, Tianjin University, Tianjin, 300072 and Department of Chemistry, Tianjin University, Tianjin, 300072 |
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| Abstract: | |
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| Keywords: | gadolinium complex schiff base cryptand crystal structure |
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