| 钨磷酸［C2H10NO］3［PW12O40］CH3CN电荷转移盐的合成、表征、光色性及非线性光学性质 |
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| 引用本文： | 牛景扬,王敬平,陈瑶.钨磷酸［C2H10NO］3［PW12O40］CH3CN电荷转移盐的合成、表征、光色性及非线性光学性质[J].无机化学学报,1999,15(3):401-404. |
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| 作者姓名： | 牛景扬 王敬平 陈瑶 |
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| 作者单位： | 1. 河南大学化学化工学院,开封,475001
2. 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 国家自然科学基金,河南省自然科学基金,河南省教委自然科学基金 |
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| 摘 要： | 杂多化合物为一类重要的多核配合物，因其优良的催化性能及其在其他领域的应用前景而受到广泛的重视［１－３］。研究发现，Ｋｅｇｇｉｎ型阴离子具有很强的接受电子能力［４］，可作为电子受体与有机给体相结合形成电荷转移盐，该类盐在光激发下可以发生电荷转移，从而表...
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| 关 键 词： | 钨磷酸 电荷转移 光色性 光学非线性 |
SYNTHESIS, CHARACTERIZATION, PHOTOCHROMISM AND NONLINEAR OPTICAL PROPERTIES OF A CHARGE TRANSFER SALT BASED ON TUNGSTOPHOSPHORIC ACID [C5H10NO]3[PW12O40]CH3CN |
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| NIU Jing-Yang,WANG Jing-Ping and CHEN Yao.SYNTHESIS, CHARACTERIZATION, PHOTOCHROMISM AND NONLINEAR OPTICAL PROPERTIES OF A CHARGE TRANSFER SALT BASED ON TUNGSTOPHOSPHORIC ACID [C5H10NO]3[PW12O40]CH3CN[J].Chinese Journal of Inorganic Chemistry,1999,15(3):401-404. |
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| Authors: | NIU Jing-Yang WANG Jing-Ping and CHEN Yao |
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| Institution: | Department of Chemistry, Henan University, Kaifeng 475000,Department of Chemistry, Henan University, Kaifeng 475000 and Coordination Chemistry Institute, State Key Labortory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | The photosensitive and SHG active charge transfer slat has been synthesized based on tungstophosphoric acid and N-methylpyrrolidone and characterized by elemental analysis, IR spectrum as well as TG-DTA. Photochromism studies show that the electron transfer takes place from the organic molecules to the polymetallic anions. Nonlinear optical properties measurements indicate that the title compound exhabits the second and third order nonlinear optical activities. |
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| Keywords: | tungstophosphoric acid charge transfer photochromism nonlinear optical properties |
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