| 三邻氯苄基锡-2-吲哚甲酸酯的合成、谱学性质和晶体结构(英) |
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| 引用本文： | 尹汉东,王其宝,薛绳才.三邻氯苄基锡-2-吲哚甲酸酯的合成、谱学性质和晶体结构(英)[J].无机化学学报,2004,20(12):1477-1480. |
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| 作者姓名： | 尹汉东 王其宝 薛绳才 |
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| 作者单位： | 聊城大学化学化工学院,聊城,252059 |
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| 基金项目： | 国家自然科学基金(No.20271025)，教育部骨干教师基金，山东省自然科学基金(No.L2003B01) |
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| 摘 要： | The tri(o-chlorobenzyl)tin ester of 2-indolylcarboxylic acid has been synthesized and characterized by elemental analysis, IR and 1H NMR. The crystal structure has been determined by X-ray single crystal diffraction. The crystal belongs to triclinic with space group P1, a=1.020 0(16) nm, b=1.125 9(18) nm, c=1.321(2) nm, α=83.10(2)°, β=67.597(18)°, γ=84.83(2)°, Z=2, V=1.391(4) nm3, Dx=1.565 Mg·m-3, μ=1.235 mm-1, F(000)=656, R=0.049 2, wR=0.131 4. In this compound, the central tin atom is rendered four-coordinated in a tetrahedral structure. The resulting structure is a monomer containing Sn-O bond length of 0.205 4(4) nm. CCDC: 236286.
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| 关 键 词： | 三邻氯苄基锡 2-吲哚甲酸 合成 晶体结构 |
Synthesis, Spectroscopic Properties and Structural Characterization of Tri(o-chlorobenzyl)tin Ester of 2-indolylcarboxylic Acid |
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| YIN Han-Dong,WANG Qi-Bao and XUE Sheng-Cai.Synthesis, Spectroscopic Properties and Structural Characterization of Tri(o-chlorobenzyl)tin Ester of 2-indolylcarboxylic Acid[J].Chinese Journal of Inorganic Chemistry,2004,20(12):1477-1480. |
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| Authors: | YIN Han-Dong WANG Qi-Bao and XUE Sheng-Cai |
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| Institution: | Department of Chemistry, Liaocheng University, Liaocheng 252059,Department of Chemistry, Liaocheng University, Liaocheng 252059 and Department of Chemistry, Liaocheng University, Liaocheng 252059 |
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| Abstract: | The tri (o-chlorobenzyl)tin ester of 2-indolylcarboxylic acid has been synthesized and characterized by ele mental analysis, IR and 1H NMR. The crystal structure has been determined by X-ray single crystal diffraction. The crystal belongs to triclinic with space group Pi, a=1.0200(16) nm, b=1.125 9(18) nm, c=1.321(2) nm, α= 83.10(2)°, β=67.597(18)°, y=84.83(2)°, Z=2, V=1.391(4) nm3, Dx=1.565 Mg·m-3,μ=1.235 mm-1, F(000)=656, R= 0.049 2, wR=0.131 4. In this compound, the central tin atom is rendered four-coordinated in a tetrahedral struc ture. The resulting structure is a monomer containing Sn-O bond length of 0.205 4(4) nm. CCDC: 236286. |
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| Keywords: | tri(2-chlorobenzyl)tin 2-indolylcarboxylic acid systhesis crystal structure |
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