| 单一手性烯烃铜(Ⅰ)配位聚合物 |
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| 引用本文： | 庞洁,王国喜,熊仁根.单一手性烯烃铜(Ⅰ)配位聚合物[J].无机化学学报,2007,23(7):1227-1229. |
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| 作者姓名： | 庞洁 王国喜 熊仁根 |
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| 作者单位： | 南京大学化学化工学院,配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 摘 要： | The solvothermal reaction of CuCl with R-(-)-1-allyl-3-methylpiperazine at 70 ℃ gives one-dimensional chain Cu-coordination polymer through olefin moiety binding to Cu atoms formulated as Cu(C8H16N2)Cl]. It is interesting to note that through Cu2Cl2 dimer unit 1 results in a supramolecular 3-dimensional coordination polymer. Powdered sample measurement of 1 reveals that 1 is second-harmonic generation (SHG) active compound. Crystal parameters for 1, space group P212121, a=0.763 1(9) nm, b=0.891 0(10) nm, c=1.494 6(17) nm, α=90°, β=90°, γ=90°, V=1.016(2) nm3, Z=2, M=478.44, Dc=1.564 Mg·m-3. CCDC: 650193.
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| 关 键 词： | 烯烃铜(Ⅰ) 水热法 配位聚合物 晶体结构 |
| 文章编号： | 1001-4861（2007）07-1227-03 |
| 修稿时间： | 2007-04-022007-06-20 |
A Homochiral Olefin-copper(Ⅰ) Coordination Polymer |
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| PANG Jie,WANG Guo-Xi and XIONG Ren-Gen.A Homochiral Olefin-copper(Ⅰ) Coordination Polymer[J].Chinese Journal of Inorganic Chemistry,2007,23(7):1227-1229. |
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| Authors: | PANG Jie WANG Guo-Xi and XIONG Ren-Gen |
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| Institution: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | The solvothermal reaction of CuCl with R-(-)-1-allyl-3-methylpiperazine at 70 ℃ gives one-dimensional chain Cu-coordination polymer through olefin moiety binding to Cu atoms formulated as Cu (C8H16N2)Cl]. It is interesting to note that through Cu2Cl2 dimer unit 1 results in a supramolecular 3-dimensional coordination polymer.Powdered sample measurement of 1 reveals that 1 is second-harmonic generation (SHG) active compound. Crystal parameters for 1, space group P212121, a=0.763 1(9) nm, b=0.891 0(10) nm, c=1.494 6(17) nm, α=90°,β=90°, γ=90°,V=1.016(2)nm3,Z=2,M=478.44,Dc=1.564 Mg·m-3.CCDC:650193. |
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| Keywords: | solvothermal coordination polymer crystal structure |
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