| 甲酰胺对有序介孔二氧化硅形貌的影响 |
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| 引用本文： | 党文修,韩书华,许 军,闫 欣,侯万国.甲酰胺对有序介孔二氧化硅形貌的影响[J].无机化学学报,2004,20(6):679-682. |
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| 作者姓名： | 党文修 韩书华 许 军 闫 欣 侯万国 |
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| 作者单位： | 1. 山东大学胶体与界面化学教育部重点实验室,济南,250100;山东警察学院,济南,250014
2. 山东大学胶体与界面化学教育部重点实验室,济南,250100 |
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| 基金项目： | 清华大学新型陶瓷与精细工艺国家重点实验室资助项目(No.KF0101) |
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| 摘 要： | At room temperature and in acidic solution, ordered mesoporous silicas with particular morphology were synthesized using cetylpyridinium chloride as the template and formamide as the cosolvent. Scanning electron microscope (SEM), small angle X-ray diffraction (SXRD), and nitrogen adsorption techniques were used to characterize the as-synthesized and calcined samples. Results showed that the samples had hexagonal mesostructure analogous to MCM-41 and relatively narrow pore-size distributions (BJH). Besides, BET surface areas of the samples were in the range of 1 000～1 250 m2·g-1 and high total pore volumes were up to 1.367 cm3·g-1. Addition of formamide affected obviously mesostructures and the morphology of the mesoporous silica. Furthermore, with the increase of the concentration of formamide, the unit-cell constant decreased and particle shape changed from gyroids to fibers.
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| 关 键 词： | 介孔 二氧化硅 形貌 甲酰胺 模板 |
| 修稿时间： | 2003年12月25 |
Effect of Formamide on the Morphologies of Ordered Mesoporous Silica |
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| DANG Wen-Xiu,HAN Shu-Hu,XU Jun,YAN Xin and HOU Wan-Guo.Effect of Formamide on the Morphologies of Ordered Mesoporous Silica[J].Chinese Journal of Inorganic Chemistry,2004,20(6):679-682. |
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| Authors: | DANG Wen-Xiu HAN Shu-Hu XU Jun YAN Xin and HOU Wan-Guo |
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| Institution: | Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100;Shandong Police College, Jinan 250014,Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100,Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100,Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100 and Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100 |
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| Abstract: | |
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| Keywords: | mesoporous silica morphology formamide template |
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