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| 检测钠离子的荧光探针：含稠合外环的硼-二吡咯亚甲基染料的合成与光物理性质研究 | |
| 引用本文： | 徐海云,沈珍,奥岛铁雄,小野昇.检测钠离子的荧光探针：含稠合外环的硼-二吡咯亚甲基染料的合成与光物理性质研究[J].无机化学学报,2006,22(5):801-807. |
| 作者姓名： | 徐海云 沈珍 奥岛铁雄 小野昇 |
| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,化学化工学院,南京,210093;淮南师范学院化学系,淮南,232001 2. 南京大学配位化学研究所,配位化学国家重点实验室,化学化工学院,南京,210093 3. 日本爱媛大学理学部,化学系,松山,790-8577,日本 |
| 基金项目： | 国家自然科学基金;国家自然科学基金;教育部霍英东教育基金 |
| 摘 要： | 本文报道了两种中位为苯并冠醚亚单元取代的含稠合外环的硼-二吡咯亚甲基染料的合成、光谱和电化学性质。研究结果表明：在荧光团中引入吸电子的酯基使化合物2成为一种高灵敏性的检测钠离子的荧光探针。 |
| 关 键 词： | 硼-二吡咯亚甲基染料 稠合外环 电子转移 荧光探针 |
| 文章编号： | 1001-4861(2006)05-0801-07 |
| 收稿时间： | 2006-02-05 |
| 修稿时间： | 2006-04-18 |
Fluorescent Probe for Na+: Synthesis and Spectroscopic Studies of Exocyclic Ring-Fused Boron Dipyrromethene Dyes |
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| XU Hai-Yun,SHEN Zhen,OKUJIMA Tetsuo and ONO Noboru.Fluorescent Probe for Na+: Synthesis and Spectroscopic Studies of Exocyclic Ring-Fused Boron Dipyrromethene Dyes[J].Chinese Journal of Inorganic Chemistry,2006,22(5):801-807. | |
| Authors: | XU Hai-Yun SHEN Zhen OKUJIMA Tetsuo and ONO Noboru |
| Institution: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;Department of Chemistry, Huainan Normal College, Huainan, Anhui 232001,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093,Department of Chemistry, Faculty of Science, Ehime University, 2-5 Bunkyo-cho, Matsuyama 790-8577, Japan and Department of Chemistry, Faculty of Science, Ehime University, 2-5 Bunkyo-cho, Matsuyama 790-8577, Japan |
| Abstract: | Two new exocyclic ring-fused boron-dipyrromethene (BDP) dyes with benzo crown ether subunit at meso-position were prepared. Their spectroscopic and electrochemical properties were investigated. The introduction of the electron withdrawing ester groups to the chromophore makes compound 2 to be a very sensitive fluorescent probe for Na+ analysis. |
| Keywords: | boron-dipyrromethene (BDP) dyes fused exocyclic rings electron transfer fluorescent sensor |
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