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CdS/TiO2纳米管复合结构的制备与光电性能研究
引用本文:向宇,付继江,郝娜,张成铖,夏进阳,彭祥,张旭明.CdS/TiO2纳米管复合结构的制备与光电性能研究[J].无机化学学报,2013,29(18).
作者姓名:向宇  付继江  郝娜  张成铖  夏进阳  彭祥  张旭明
作者单位:武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081;武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081;武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081;武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081;武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081;武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081;武汉科技大学材料与冶金学院, 湖北省耐火材料与高温陶瓷重点实验室, 武汉 430081
基金项目:国家自然科学基金(No.50902104)资助项目
摘    要:利用阳极氧化法在钛金属基体表面制备一层TiO2纳米管阵列薄膜, 然后通过水热反应在TiO2纳米管上负载CdS纳米粒子, 形成CdS/TiO2纳米管的复合结构。利用SEM、XRD、XPS、UV-Vis等手段对其形貌和结构进行表征。进一步考察了CdS/TiO2纳米管的光电性能和光催化活性, 结果表明, 相比于TiO2纳米管, CdS/TiO2纳米管复合结构在紫外光和可见光下都具有更好的光催化活性及光电性能。

关 键 词:CdS/TiO2纳米管  水热  光电化学性能
修稿时间:2/7/2013 12:00:00 AM

Fabrication and Photoelectrochemical Performance of CdS/TiO2 Nanocomposite
XIANG Yu,FU Ji-Jiang,HAO N,ZHANG Cheng-Cheng,XIA Jin-Yang,PENG Xiang and ZHANG Xu-Ming.Fabrication and Photoelectrochemical Performance of CdS/TiO2 Nanocomposite[J].Chinese Journal of Inorganic Chemistry,2013,29(18).
Authors:XIANG Yu  FU Ji-Jiang  HAO N  ZHANG Cheng-Cheng  XIA Jin-Yang  PENG Xiang and ZHANG Xu-Ming
Institution:Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China;Hubei Province Key Laboratory of Refractories and Ceramics, College of Materials Science and Metallurgical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
Abstract:CdS nanoparticles were deposited directly into the anodic TiO2 nanotubes via a simple hydrothermal method. The morphology and the structures were characterized by field-emission scanning electron microscopy(FESEM), X-ray diffraction(XRD), energy dispersive spectrometer(EDS) and ~UV-Vis reflective spectrum(UV-Vis). The photoelectrochemical properties of TiO2 and CdS/TiO2 catalysts were studied which indicates that compared with pure TiO2 nanotube catalyst, CdS/TiO2 the photocatalytic activity of CdS/TiO2 composite photocatalyst was improved markedly both under ultraviolet and visible light.
Keywords:CdS/TiO2 nanotubes  hydrothermal synthesis method  photoelectrochemical performance
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