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新型含金属元素二胺的合成与表征
引用本文:仇武林,曾文祥,李灿,邓利君,陆路德,汪信,戴庆平.新型含金属元素二胺的合成与表征[J].无机化学学报,1993,9(3):297-302.
作者姓名:仇武林  曾文祥  李灿  邓利君  陆路德  汪信  戴庆平
作者单位:南京理工大学材料化学研究室 南京210014 (仇武林,曾文祥,李灿,邓利君,陆路德,汪信),南京大学现代分析中心 南京210008(戴庆平)
基金项目:国家教委优秀年轻教师资助项目
摘    要:本文分别用液相法和固相法合成了一系列含不同金属元素的二胺,并通过红外光谱,~1HNMR、~(13)CNMR,紫外光谱,电化学分析及元素分析对其进行表征,还通过DSC和TG对其热性能进行了研究,结果发现这些二胺具有良好的耐热性,是合成一些耐热高聚物的优良原料.

关 键 词:金属元素二胺  表征  合成
收稿时间:1992/5/29 0:00:00

SYNTHESES AND CHARACTERIZATION OF NOVEL METAL-CONTAINING DIAMINES
Qiu Wulin,Zeng Wenxiang,Li Can,Deng Lijun,Lu Lude,Wang Xin and Dai Qingping.SYNTHESES AND CHARACTERIZATION OF NOVEL METAL-CONTAINING DIAMINES[J].Chinese Journal of Inorganic Chemistry,1993,9(3):297-302.
Authors:Qiu Wulin  Zeng Wenxiang  Li Can  Deng Lijun  Lu Lude  Wang Xin and Dai Qingping
Institution:Material Chemistry Laboratory, Nanjin University of Science and Technology, Nanjing, 210014,Material Chemistry Laboratory, Nanjin University of Science and Technology, Nanjing, 210014,Material Chemistry Laboratory, Nanjin University of Science and Technology, Nanjing, 210014,Material Chemistry Laboratory, Nanjin University of Science and Technology, Nanjing, 210014,Material Chemistry Laboratory, Nanjin University of Science and Technology, Nanjing, 210014,Material Chemistry Laboratory, Nanjin University of Science and Technology, Nanjing, 210014 and Modern Analysis Centre, Nanjing University, Nanjing, 210008
Abstract:A series of metal-containing diamines were prepared by both solution and solid reactions. Various metals were used, such as Cu2+, Co2+, Pb2+ etc. The structures of diamines were characterized by IR, 1HNMR, 13CNMR and UV. Their thermal properties were investigated by DSC and TG. It was found that these diamines had higher decomposition temperture and may be used for the preparation of some heat-resistance polymers.
Keywords:metal-containing diamine  solid  solution  structure characterization  heat-resistance  
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