| 蒸汽相法硼硅MFI沸石的合成与表征 |
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| 引用本文： | 董晋湘,赵兴国,周锋,刘世政,顾永达,吴锋.蒸汽相法硼硅MFI沸石的合成与表征[J].无机化学学报,1995,11(1):73-77. |
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| 作者姓名： | 董晋湘 赵兴国 周锋 刘世政 顾永达 吴锋 |
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| 作者单位： | 太原工业大学，太原市地质矿产局，中国科学院山西煤炭化学研究所，北京理工大学化学与材料工程学院 |
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| 摘 要： | 在三乙胺（Ｅｔ３Ｎ）－乙二胺（ＥＤＡ）－Ｈ２Ｏ蒸汽相中，无定形凝胶Ｎａ２Ｏ－Ｂ２Ｏ２－ＳｉＯ２－Ｈ２Ｏ晶化生成硼硅ＭＦＩ（ＺＳＭ—５）沸石．研究了硼硅ＭＦＩ沸石的适宜晶化条件，以及氯化钠、碳酸钠和磷酸钠取代氢氧化钠作为钠源的影响．晶体结构参数、１１ＢＮＭＲ、ＦＴ－ＩＲ的结果表明，由蒸汽相法合成的硼硅ＭＦＩ沸石，其硼原子进入了沸石骨架．
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| 关 键 词： | 硼硅MFI沸石，蒸汽相法，合成，表征 |
| 收稿时间： | 1994/4/12 0:00:00 |
SYSTHESIS AND CHARACTERIZATION ON B-Si MFI ZEOLITE FROM THE VAPOUR PHASE METHOD |
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| Dong Jinxiang,Zhao Xingguo,Zhou Feng,Liu Shizheng,Gu Yongda and Wu Feng.SYSTHESIS AND CHARACTERIZATION ON B-Si MFI ZEOLITE FROM THE VAPOUR PHASE METHOD[J].Chinese Journal of Inorganic Chemistry,1995,11(1):73-77. |
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| Authors: | Dong Jinxiang Zhao Xingguo Zhou Feng Liu Shizheng Gu Yongda and Wu Feng |
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| Institution: | Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024,Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024,Research Institute of Special Chemicals, Taiyuan University of Technology, Taiyuan 030024,Taiyuan Bureau of Geology and Miners, Taiyuan 030006,Insrirure of Coal Chemistry, Acadamy of Sciences of China, Taiyuan 030001 and College of Chemical Engineering and Materials, Beijing Institute of Technology, 100081 |
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| Abstract: | morphous gel-Na2O-B2O3-SiO2-H2O grows into zeolite B-Si MFI in vapour-tricthylaminc (Et3N)-ethyldiamine (EDA)-H2O. They are studied suitable crystalline conditions for B-Si MFI and the influence of which NaCl, Na2CO3, and Na3PO4 replace NaOH as sodium source. The results of crystalline structure parameter, 11B NMR, and FT-IR illustrate that boron atoms of B-Si MFI zeolite from the vapour phase method are inside of zeolitic framework. |
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| Keywords: | B-Si MFI zeolite vapour phase method ysnthesis characterization |
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