| 铋配合物[Bi(S2CNC5H10)2(NO3)]·[1，10-Phen]·0.5H2O的合成及晶体结构 |
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| 引用本文： | 尹汉东,王传华,许福泉.铋配合物[Bi(S2CNC5H10)2(NO3)]·[1，10-Phen]·0.5H2O的合成及晶体结构[J].无机化学学报,2004,20(3):345-348. |
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| 作者姓名： | 尹汉东 王传华 许福泉 |
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| 作者单位： | 聊城大学化学系,聊城,252059 |
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| 基金项目： | 国家自然科学基金(No.20271025),教育部骨干教师基金和山东省自然科学基金(No.L2003B01)资助项目. |
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| 摘 要： | The bismuth complex with dithiopiperdylcarbamate Bi(S2CNC5H10)2(NO3)]·1，10-Phen]·0.5H2O was synthesized. The crystal and molecular structure were determined by X-ray single crystal diffraction. The crystal belongs to monoiclinic with space group C2/c, a=3.140(2) nm, b=1.176 4(9) nm, c=2.021 6(15) nm, β=103.081(12)°, V=5.713(7) nm3, Z=8, F(000)=3064, Dc=1.815 g·cm-3, μ=6.502mm-1. The final R1=0.0332, wR2=0.040 3. In the complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. CCDC: 222655.
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| 关 键 词： | 铋配合物 哌啶氨荒酸 合成 晶体结构 |
| 修稿时间： | 2003年9月2日 |
Synthesis and Crystal Structure of the Bismuth Complex [Bi(S2CNC5H10)2(NO3)]· [1,10-Phen]· 0.5H2O |
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| YIN Han-Dong,WANG Chuan-Hua and XU Fu-Quan.Synthesis and Crystal Structure of the Bismuth Complex [Bi(S2CNC5H10)2(NO3)]· [1,10-Phen]· 0.5H2O[J].Chinese Journal of Inorganic Chemistry,2004,20(3):345-348. |
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| Authors: | YIN Han-Dong WANG Chuan-Hua and XU Fu-Quan |
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| Institution: | Department of Chemistry, Liaocheng University, Liaocheng 252059,Department of Chemistry, Liaocheng University, Liaocheng 252059 and Department of Chemistry, Liaocheng University, Liaocheng 252059 |
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| Abstract: | |
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| Keywords: | bismuth complex dithiopiperdylcarbamate synthesis crystal structure |
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