| 以螺吡喃衍生物原位合成的席夫碱配体的铜配合物的制备及表征 |
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| 引用本文： | 张少壮,马驰枭,郭海洋,佘剑辉,张俊勇,石彦波,李国栋,任小明,谢景力.以螺吡喃衍生物原位合成的席夫碱配体的铜配合物的制备及表征[J].无机化学学报,2022,38(2):353-360. |
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| 作者姓名： | 张少壮 马驰枭 郭海洋 佘剑辉 张俊勇 石彦波 李国栋 任小明 谢景力 |
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| 作者单位： | 南京工业大学化学与分子工程学院;嘉兴学院生物与化学工程学院;嘉兴市中医医院中心实验室;吉林大学化学学院 |
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| 基金项目： | 国家自然科学基金(No.21771088);浙江省自然科学基金(No.LY20B010005);无机合成与制备化学国家重点实验室开放基金(No.2020?9)资助。 |
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| 摘 要： | 在Cu2+存在条件下,利用N?羟乙基?3,3?二甲基?6?硝基吲哚啉螺吡喃分别与乙二胺分子或1,3?丙二胺分子(1,3?diaminopropane,1,3?DAP)发生原位反应,得到了席夫碱配体双?((2?(甲基亚胺甲基)?4?硝基苯酚))阴离子(L1)或2?((3?胺基丙基亚胺)?甲基)?4?硝基苯酚阴离子(L2)的铜配合物Cu(L1)](1)和Cu(L2)(1,3?DAP)]NO3(2)。用红外光谱、单晶X射线衍射和粉末X射线衍射对2种配合物进行了相关表征。在降解有机染料分子的过程中,观察到2种配合物具有一定的光催化性能。
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| 关 键 词： | 席夫碱配体 原位反应 螺吡喃 光催化活性 |
| 收稿时间： | 2021/1/15 0:00:00 |
| 修稿时间： | 2021/11/8 0:00:00 |
Preparation and Characterization of Copper Complexes of Schiff Base Ligands Synthesized In Situ from Spiropyran Derivative |
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| ZHANG Shao-Zhuang,MA Chi-Xiao,GUO Hai-Yang,SHE Jian-Hui,ZHANG Jun-Yong,SHI Yan-Bo,LI Guo-Dong,REN Xiao-Ming,XIE Jing-Li.Preparation and Characterization of Copper Complexes of Schiff Base Ligands Synthesized In Situ from Spiropyran Derivative[J].Chinese Journal of Inorganic Chemistry,2022,38(2):353-360. |
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| Authors: | ZHANG Shao-Zhuang MA Chi-Xiao GUO Hai-Yang SHE Jian-Hui ZHANG Jun-Yong SHI Yan-Bo LI Guo-Dong REN Xiao-Ming XIE Jing-Li |
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| Institution: | (State Key Laboratory of Materials-Oriented Chemical Engineering,College of Chemistry and Molecular Engineering,Nanjing Tech University,Nanjing 211816,China;College of Biological,Chemical Sciences and Engineering,Jiaxing University,Jiaxing,Zhejiang 314001,China;Central Laboratory of Jiaxing Traditional Chinese Medicine Hospital,Jiaxing Key Laboratory of Diabetic Angiopathy Research,Jiaxing,Zhejiang 314000,China;State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,College of Chemistry,Jilin University,Changchun 130012,China) |
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| Abstract: | By virtue of Schiff base ligands bis(2-(methyliminomethyl)-4-nitro-phenol) dianion (L1)/2-((3-aminopropylimino)-methyl)-4-nitro-phenol monoanion (L2) that derived from photochromic molecule 2-(3'',3''-dimethyl-6-nitrospiro(chromene-2,2''-indolin)-1''-yl)ethanol, two metal-organic complexesCu(L1)] (1) andCu(L2)(1,3-DAP)]NO3 (2) have been successfully fabricated through in situ ligand reaction in the presence of Cu2+. These complexes were characterized by IR, single-crystal X-ray diffraction, and powder X-ray diffraction. Additionally, certain photocatalytic properties of the two complexes for the degradation of organic dye molecules have been observed. |
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| Keywords: | Schiff base ligand in situ reaction spiropyran photocatalytic activity |
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