| 异亚硝基乙酰乙酸乙酯亚胺Pd(Ⅱ)配合物的合成、表征和tran Pd(p-CH3C6H4-IEAI)2的晶体结构 |
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| 引用本文： | 冯云龙,刘世雄.异亚硝基乙酰乙酸乙酯亚胺Pd(Ⅱ)配合物的合成、表征和tran Pd(p-CH3C6H4-IEAI)2的晶体结构[J].无机化学学报,2002,18(9):929-932. |
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| 作者姓名： | 冯云龙 刘世雄 |
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| 作者单位： | 浙江师范大学物理化学研究所,金华 321004;福州大学中心实验室,福州 350002,福州大学中心实验室,福州 350002 |
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| 摘 要： | Six palladium(Ⅱ) complexes with isonitrosoethylacetoacetate imine Schiff base ligands, Pd(R-IEAI)2, were prepared and characterized by IR, Raman and electronic spectra. Complex tran Pd(p-CH3C6H4-IEAI)2 (2) cry- stallizes in the monoclinic system, space group P21/c,with a=1.2002(2),b=0.9972(2),c=1.1121(2)nm,β=90.43(3)°,Z=2,F(000)=616,μ=7.44cm-1. The final R and wR are 0.0244 and 0.0625 for 2620 ob-served reflections with I≥2σ(I), respectively. The geometry around the Pd(Ⅱ) ions in those complexes has a distorted PdN4 square plane, the Schiff base ligands R-IEAI- being coordinated through their oximino-nitrogen atoms and imino-nitrogen atoms.
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| 关 键 词： | Pd(Ⅱ)配合物 异亚硝基乙酰乙酸乙酯 Schiff碱 晶体结构 |
| 修稿时间： | 2002年4月2日 |
Syntheses, Spectral Properties of Palladium? Complexes with IsonitrosoethylacetoacetateImine Ligands, and Crystal Structure of tran Pd(p CH3C6H4 IEAI)2 |
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| FENG Yun-Long and LIU Shi-Xiong.Syntheses, Spectral Properties of Palladium? Complexes with IsonitrosoethylacetoacetateImine Ligands, and Crystal Structure of tran Pd(p CH3C6H4 IEAI)2[J].Chinese Journal of Inorganic Chemistry,2002,18(9):929-932. |
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| Authors: | FENG Yun-Long and LIU Shi-Xiong |
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| Institution: | Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004;Laboratory Center, Fuzhou University, Fujian 350002 and Laboratory Center, Fuzhou University, Fujian 350002 |
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| Abstract: | |
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| Keywords: | palladium? complex isonitrosoethylacetoacetate imine Schiff base crystal structure |
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