| ZnO微结构调控及其光学性能的研究 |
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| 引用本文： | 刘海霞,黄柏标,王泽岩,秦晓燕,张晓阳,俞娇仙.ZnO微结构调控及其光学性能的研究[J].无机化学学报,2011,27(4):752-758. |
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| 作者姓名： | 刘海霞 黄柏标 王泽岩 秦晓燕 张晓阳 俞娇仙 |
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| 作者单位： | 山东大学晶体材料国家重点实验室,济南,250100 |
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| 基金项目： | 973国家重点基础研究项目，国家自然科学基金 |
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| 摘 要： | 氧化锌不同形貌的合成与控制可以通过一个简单的溶剂热反应来实现,其中乙醇作溶剂,酒石酸做添加剂。通过控制酒石酸的加入量,可以有效地控制ZnO的形貌、尺寸以及到更复杂结构的转变。同时提出了不同形貌ZnO可能的生长机制,并利用FTIR谱进一步证实了酒石酸对ZnO生长的影响。另外,由光致发光光谱可以看出,不同的ZnO形貌,发光性能会有所不同,总体上说,所得ZnO的发光区域主要集中在紫光波段和橙光波段。
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| 关 键 词： | 氧化锌 微结构 机理 光学性能 |
Synthesis and Optical Properties of Assembly-Controlled ZnO Structures |
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| LIU Hai-Xi,HUANG Bai-Biao,WANG Ze-Yan,QIN Xiao-Yan,ZHANG Xiao-Yang and YU Jiao-Xian.Synthesis and Optical Properties of Assembly-Controlled ZnO Structures[J].Chinese Journal of Inorganic Chemistry,2011,27(4):752-758. |
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| Authors: | LIU Hai-Xi HUANG Bai-Biao WANG Ze-Yan QIN Xiao-Yan ZHANG Xiao-Yang and YU Jiao-Xian |
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| Institution: | State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China,State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China,State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China,State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China,State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China and State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China |
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| Abstract: | A facile solvothermal synthesis of ZnO architectures has been developed using ethanol as solvent and tartaric acid as the additive. The variational quantities of tartaric acid controlled the ZnO morphology and shape as well as the self-assembly of ZnO crystals into complex architectures. Possible growth mechanisms of obtained ZnO with different morphologies were proposed. The influence of tartaric acid to ZnO growth was further indicated by FTIR spectra. In addition, the photoluminescence (PL) properties of these ZnO samples were investigated at room temperature, which indicated that the ZnO morphology could influence its optical property. On the whole, the fluorescence was violet emission and orange emission primarily. |
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| Keywords: | zinc oxide microstructures mechanism optical property |
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