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具有一维梯度直径的金属银纳米线的制备与结构表征
引用本文:张晓光,袁志好,徐丽萍.具有一维梯度直径的金属银纳米线的制备与结构表征[J].无机化学学报,2006,22(10):1916-1920.
作者姓名:张晓光  袁志好  徐丽萍
作者单位:天津理工大学纳米材料与技术研究中心,天津,300191;天津市光电显示材料与器件重点实验室,天津,300191
基金项目:国家自然科学基金;天津市重点学科建设基金
摘    要:Since the conceptoffunctionally graded m aterials(FG M)is proposed1,2],m uch attention has been paid toFG M studies.Generally,FG M s were designed with thegradientdistribution ofcom position and structure,andthe graded structure of FG M is achieved by acom position gradient from one side of m aterials to theother,resulting in gradientproperties.Itis well鄄knownthat properties of nanom eter鄄sized m aterials stronglydepend on their sizes.Such size effect offers a newconcept for the design…

关 键 词:银梯度纳米线    尺寸梯度    多孔氧化铝模板    电化学沉积
文章编号:1001-4861(2006)10-1916-05
收稿时间:2006-05-24
修稿时间:2006-08-06

Preparation and Characterization of Ag Nanowires with Gradient Sizes
ZHANG Xiao-Guang,YUAN Zhi-Hao and XU Li-Ping.Preparation and Characterization of Ag Nanowires with Gradient Sizes[J].Chinese Journal of Inorganic Chemistry,2006,22(10):1916-1920.
Authors:ZHANG Xiao-Guang  YUAN Zhi-Hao and XU Li-Ping
Institution:Nanomaterials & Nanotechnology Research Center, Tianjin University of Technology, Tianjin 300191;Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin 300191,Nanomaterials & Nanotechnology Research Center, Tianjin University of Technology, Tianjin 300191;Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin 300191 and Nanomaterials & Nanotechnology Research Center, Tianjin University of Technology, Tianjin 300191;Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin 300191
Abstract:A new one-dimensional gradient material with graded sizes was prepared. A two-step anodic oxidation of high purity aluminum was used to fabricate porous alumina templates with graded pore sizes. Based on the templates, metal silver graded nanowires were obtained by electrochemical deposition. SEM and TEM results show that the resulted metal silver nanowires have obvious graded diameters with gradient ranging from about 12 to 31 nm along the nanowire direction, and are single-crystalline with a preferential growth along <100> direction.
Keywords:silver graded nanowire  size gradient  anodic aluminum oxide template  electrochemical deposition
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