| 双核Fe配合物[(η5-C5H4)C6H10(C4H3S)Fe(CO)2]2的合成和晶体结构 |
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| 引用本文： | 田利娟,马志宏,刘晓焕,韩占刚,郑学忠,林 进.双核Fe配合物[(η5-C5H4)C6H10(C4H3S)Fe(CO)2]2的合成和晶体结构[J].无机化学学报,2011,27(3):571-574. |
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| 作者姓名： | 田利娟 马志宏 刘晓焕 韩占刚 郑学忠 林 进 |
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| 作者单位： | 1. 河北师范大学化学与材料科学学院,石家庄,050016
2. 河北医科大学基础医学院,石家庄,050017 |
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| 基金项目： | 河北省自然科学基金(No.B2008000150); 河北师范大学博士启动基金(No.L2005B18)和河北师范大学重点基金(No.L2009Z06)资助项目 |
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| 摘 要： | 由侧链带有噻吩的环戊二烯基配体C5H5C6H10C4H3S与Fe(CO)5在二甲苯中加热回流,合成了1个新颖的四羰基二铁配合物(η5-C5H4)C6H10(C4H3S)Fe(CO)2]2。通过元素分析、IR、1H NMR对其结构进行了表征,用X-射线单晶衍射确定了其结构。X-射线单晶衍射表明配合物中有2个桥羰基和2个端羰基,Fe-Fe的键长为0.25465(10)nm。
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| 关 键 词： | 羰基铁 结构 环戊二烯基 合成 |
Synthesis and Crystal Structure of Binuclear Iron Complex [(η5-C5H4) C6H10(C4H3S)Fe(CO)2]2 |
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| TIAN Li-Juan,MA Zhi-Hong,LIU Xiao-Huan,HAN Zhan-Gang,ZHENG Xue-Zhong and LIN Jin.Synthesis and Crystal Structure of Binuclear Iron Complex [(η5-C5H4) C6H10(C4H3S)Fe(CO)2]2[J].Chinese Journal of Inorganic Chemistry,2011,27(3):571-574. |
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| Authors: | TIAN Li-Juan MA Zhi-Hong LIU Xiao-Huan HAN Zhan-Gang ZHENG Xue-Zhong and LIN Jin |
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| Institution: | College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China,College of Basic Medicine, Hebei Medical University, Shijiazhuang 050017, China,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China,College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China and College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050016, China |
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| Abstract: | The reaction of the thienyl side chain functionalized cyclopentadienyl ligand C5H5C6H10C4H3S with Fe(CO)5 in refluxing xylene gave the novel cyclopentadienyl tetracarbonyl diiron compound (η5-C5H4)C6H10(C4H3S)Fe(CO)2]2.The structure of the compound was characterized by elemental analysis, IR, 1H NMR spectra and X-ray single crystal diffraction. The X-ray crystal structure indicates the structure with bridging and terminal CO groups and the bond length of Fe-Fe is 0.254 65(10) nm. CCDC: 768950. |
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| Keywords: | carbonyl iron structure cyclopentadienyl synthesis |
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