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分子导线的研究进展
引用本文:张相宜,郑 启,钱晨熹,左景林.分子导线的研究进展[J].无机化学学报,2011,27(8):1451-1464.
作者姓名:张相宜  郑 启  钱晨熹  左景林
作者单位:南京大学配位化学研究所,配位化学国家重点实验室,南京210093
基金项目:国家自然科学基金(No.20725104和91022031); 国家重点基础研究发展规划项目(No.2011CB808704)资助项目
摘    要:随着电子设备和器件的尺寸越来越小,基于分子的器件研究引起了人们的广泛关注。其中分子导线具有小尺寸、多样性、性能可调等优点,因而被赋予了许多潜在的应用前景。本文总结了分子导线的概念和分类,重点介绍了两端为金属配合物和含Ru-Ru金属键单元的共轭炔基分子导线,并对四硫富瓦烯类分子的独特性质和它在分子导线中的应用进行了简单小结。

关 键 词:分子导线  金属炔基化合物  钌金属键配合物  四硫富瓦烯  分子器件

Some New Progress on Molecular Wires
ZHANG Xiang-Yi,ZHENG Qi,QIAN Chen-Xi and ZUO Jing-Lin.Some New Progress on Molecular Wires[J].Chinese Journal of Inorganic Chemistry,2011,27(8):1451-1464.
Authors:ZHANG Xiang-Yi  ZHENG Qi  QIAN Chen-Xi and ZUO Jing-Lin
Institution:Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China,Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China and Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China
Abstract:With the miniaturization of electronic devices, molecule-based devices have attracted increasing interest. Molecular wires, an essential part of it, have considerable advantages over the traditional wires including their nanoscale size, diversity and tunability, which give them great potential for application. This paper reviews the concept and classification of molecular wires, the recent progress on the conjugated hydrocarbon chains that have either metal coordination compounds at the terminals or the Ru-Ru bonding complexes. Some work on the electrical properties of tetrathiafulvalene (TTF) and its derivatives for molecular wires is also described.
Keywords:molecular wires  metal-alkynyl compounds  ruthenium metal-metal bonding complexes  tetrathiafulvalene  molecular device
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