首页 | 本学科首页   官方微博 | 高级检索  
     

金刚乙胺水杨醛Schiff碱锌(Ⅱ)配合物的合成、表征、晶体结构和热分解动力学研究
引用本文:赵国良,冯云龙,刘幸海. 金刚乙胺水杨醛Schiff碱锌(Ⅱ)配合物的合成、表征、晶体结构和热分解动力学研究[J]. 无机化学学报, 2005, 21(4): 598-602
作者姓名:赵国良  冯云龙  刘幸海
作者单位:浙江师范大学化学与生命科学学院,金华,321004
基金项目:浙江省教育厅基金资助项目(No.20030711)。
摘    要:A Zinc(Ⅱ) complex [ZnCl2(HL)2] with Schiff base HL derived from rimantadine and salicylaldehyde was synthesized and characterized by elemental analysis, infrared spectra, 1H NMR spectra,molar conductance, ultraviolet and visible spectra, thermal analysis. Its structure was determined by single crystal X-ray diffraction method. The complex, C38H50Cl2N2O2Zn, crystallizes in the orthorhombic system, space group Aba2 with a=1.381 7(3), b=2.275 0(5), c=1.145 0(2) nm, V=3.599(1) nm3, Z=4, Mr=653.79, F(000)=1 496, Dc=1.301 kg·m-3, μ(Mo )=0.866 mm-1. The kinetic parameters were obtained from the analysis of TG curve by integral methods. The functions of thermal decomposition reaction mechanism are: F(α)=[1-(1-α)1/3]2, and kinetic compensation effect equation lnA=0.019 1E-0.142 7. CCDC: 253297.

关 键 词:金刚乙胺; 水杨醛; Schiff碱; Zn(Ⅱ)配合物; 晶体结构; 热分解动力学
文章编号:1001-4861(2005)04-0598-05
收稿时间:2004-08-18
修稿时间:2004-08-18

Synthesis, Characterization, Crystal Structure and Kinetics of Thermal Decomposition of Zn(Ⅱ) Complex
ZHAO Guo-Liang,FENG Yun-Long and LIU Xing-Hai. Synthesis, Characterization, Crystal Structure and Kinetics of Thermal Decomposition of Zn(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(4): 598-602
Authors:ZHAO Guo-Liang  FENG Yun-Long  LIU Xing-Hai
Affiliation:College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004,College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004 and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004
Abstract:
Keywords:rimantadine  salicylaldehyde  Schiff base  Zn complex  crystal structure  thermal decomposition kinetics  
本文献已被 CNKI 万方数据 等数据库收录!
点击此处可从《无机化学学报》浏览原始摘要信息
点击此处可从《无机化学学报》下载全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号