| 2-苯亚胺官能化吲哚基铕-胺基配合物与芳基取代甲脒的反应性 |
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| 引用本文： | 冯志君,崔巧玉,韦芸,周双六,吴运军,王少印.2-苯亚胺官能化吲哚基铕-胺基配合物与芳基取代甲脒的反应性[J].无机化学学报,2013,29(18). |
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| 作者姓名： | 冯志君 崔巧玉 韦芸 周双六 吴运军 王少印 |
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| 作者单位： | 皖南医学院医用基础化学教研室, 芜湖 241002;功能分子固体教育部重点实验室, 安徽师范大学化学与材料科学学院分子材料实验室, 芜湖 24100,皖南医学院医用基础化学教研室, 芜湖 241002,功能分子固体教育部重点实验室, 安徽师范大学化学与材料科学学院分子材料实验室, 芜湖 24100,功能分子固体教育部重点实验室, 安徽师范大学化学与材料科学学院分子材料实验室, 芜湖 24100,皖南医学院医用基础化学教研室, 芜湖 241002,皖南医学院医用基础化学教研室, 芜湖 241002 |
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| 基金项目： | 皖南医学院博士科研启动基金（No.rcqd201613）和国家级大学生创新训练项目（No.201510368021）资助。 |
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| 摘 要： | 2-（苯亚胺基次甲基）吲哚铕-胺基配合物η1：η1-2-（C6H5NH=CH）C8H5N]2EuN（SiMe2）2]（1）与二芳基取代甲脒（2，6-R2C6H3N=CHNH（C6H3R2-2，6）（R=iPr（2），Me（3））经过配体交换反应，分别得到了含吲哚基脒基铕配合物η1：η1-2-（C6H5NH=CH）C8H5N]Eu（η3-2，6-iPr2C6H3）N=CHN（C6H3iPr2-2，6）]N（SiMe2）2]（4）和含脒基的稀土铕配合物（η3-2，6-Me2C6H3）N=CHN（C6H3Me2-2，6）]2EuN（SiMe2）2]（5）。结果表明，脒基的位阻显著影响了吲哚基稀土金属胺基配合物与二芳基取代甲脒的配体交换反应。配合物4和5通过IR、元素分析和X射线单晶衍射分析进行了表征。
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| 关 键 词： | 稀土金属 铕 吲哚基配体 胺基配合物 |
| 收稿时间： | 2016/8/14 0:00:00 |
| 修稿时间： | 2016/11/2 0:00:00 |
Reactivity of 2-Phenylimino-Functionalized Indolyl Europium Amide with Diaryl-Substitued Formamidines |
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| FENG Zhi-Jun,CUI Qiao-Yu,WEI Yun,ZHOU Shuang-Liu,WU Yun-Jun and WANG Shao-Yin.Reactivity of 2-Phenylimino-Functionalized Indolyl Europium Amide with Diaryl-Substitued Formamidines[J].Chinese Journal of Inorganic Chemistry,2013,29(18). |
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| Authors: | FENG Zhi-Jun CUI Qiao-Yu WEI Yun ZHOU Shuang-Liu WU Yun-Jun and WANG Shao-Yin |
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| Institution: | Department of Chemistry, Wannan Medical College, Wuhu, Anhui 241002, China;Key Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China,Department of Chemistry, Wannan Medical College, Wuhu, Anhui 241002, China,Key Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China,Key Laboratory of Functionalized Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China,Department of Chemistry, Wannan Medical College, Wuhu, Anhui 241002, China and Department of Chemistry, Wannan Medical College, Wuhu, Anhui 241002, China |
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| Abstract: | |
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| Keywords: | rare-earth metal europium indolyl ligand amido complex |
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