| 基于3,5-二((4'-羧基苄基)氧)苯甲酸和4'-(4-吡啶基)-2,2':6',2"-三联吡啶为混合配体的两个配合物的水热合成与晶体结构 |
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| 引用本文： | 乔宇,尉兵,王璐瑶,李秀颖,车广波,刘春波,张兴晶.基于3,5-二((4'-羧基苄基)氧)苯甲酸和4'-(4-吡啶基)-2,2':6',2"-三联吡啶为混合配体的两个配合物的水热合成与晶体结构[J].无机化学学报,2016,32(7):1261-1266. |
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| 作者姓名： | 乔宇 尉兵 王璐瑶 李秀颖 车广波 刘春波 张兴晶 |
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| 作者单位： | 吉林师范大学化学学院, 四平 136000;环境友好材料制备与应用教育部重点实验室, 长春 130103,吉林师范大学化学学院, 四平 136000,吉林师范大学化学学院, 四平 136000,吉林师范大学化学学院, 四平 136000;环境友好材料制备与应用教育部重点实验室, 长春 130103,吉林师范大学化学学院, 四平 136000;环境友好材料制备与应用教育部重点实验室, 长春 130103,江苏大学绿色化学与化工技术研究院, 镇江 212013,吉林师范大学化学学院, 四平 136000;环境友好材料制备与应用教育部重点实验室, 长春 130103 |
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| 基金项目： | 国家自然科学基金（No.21576112）、吉林省科技厅（No.20130521019JH,201215219,20150623024TC-19）、吉林省教育厅（吉教科合字[2014]第152号）和四平市科技局（No.2015049）资助项目。 |
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| 摘 要： | 在水热条件下,以3,5-二（（4''-羧基苄基）氧）苯甲酸（H3bcb）和4''-（4-吡啶基）-2,2''：6'',2"-三联吡啶（PYTPY）为混合配体构筑了2个过渡金属配合物Co（H2bcb）2（PYTPY）]n （1）和Mn（H2bcb）2（PYTPY）]n （2）,利用元素分析、红外光谱以及单晶X射线衍射表征其结构。分析表明配合物1和2为一维链状结构。此外,2个配合物展示了优良的热稳定性。磁化率的测试结果表明,配合物1和2在2 K和8 K以下时展示了反铁磁相互作用。
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| 关 键 词： | 过渡金属配合物 3 5-二((4''-羧基苄基)氧)苯甲酸 4''-(4-吡啶基)-2 2'':6'' 2"-三联吡啶 晶体结构 磁性 |
| 收稿时间： | 2016/1/20 0:00:00 |
| 修稿时间： | 2016/5/19 0:00:00 |
Hydrothermal Syntheses and Crystal Structures of Two Complexes Constructed from 3,5-Bis((4'-carboxylbenzyl)oxy)benzoic Acid and 4'-(4-Pyridyl)-2,2':6',2"-terpyridine Mixed Ligands |
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| QIAO Yu,WEI Bing,WANG Lu-Yao,LI Xiu-Ying,CHE Guang-Bo,LIU Chun-Bo and ZHANG Xing-Jing.Hydrothermal Syntheses and Crystal Structures of Two Complexes Constructed from 3,5-Bis((4'-carboxylbenzyl)oxy)benzoic Acid and 4'-(4-Pyridyl)-2,2':6',2"-terpyridine Mixed Ligands[J].Chinese Journal of Inorganic Chemistry,2016,32(7):1261-1266. |
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| Authors: | QIAO Yu WEI Bing WANG Lu-Yao LI Xiu-Ying CHE Guang-Bo LIU Chun-Bo and ZHANG Xing-Jing |
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| Institution: | College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China,College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China,College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China,College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China,College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China,Institute of Green Chemistry & Chemical Technology, Jiangsu University, Zhenjiang, Jiangsu 212013, China and College of Chemistry, Jilin Normal University, Siping, Jilin 136000, China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China |
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| Abstract: | Two transition metal complexes based on 3,5-bis((4''-carboxylbenzyl)oxy)benzoic acid (H3bcb) and 4''-(4-pyridyl)-2,2'':6'',2"-terpyridine (PYTPY) mixed ligands, namely, Co(H2bcb)2(PYTPY)]n (1) and Mn(H2bcb)2(PYTPY)]n (2), have been synthesized under hydrothermal conditions and characterized by elemental analysis, infrared spectrum and single-crystal X-ray diffraction. Complexes 1 and 2 exhibit one-dimensional chain structures, respectively. Furthermore, these two complexes exhibit excellent thermal stabilities. They also display antiferromagnetic interaction below 2 K and 8 K confirmed through magnetic susceptibility measurements. |
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| Keywords: | transition metal complex 3 5-bis((4''-carboxylbenzyl)oxy)benzoic acid 4''-(4-pyridyl)-2 2'':6'' 2"-terpyridine crystal structure magnetic property |
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