| 阴离子对构筑锌的肼配位卤族化合物的影响 |
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| 引用本文： | 董亚杰,王如骥,彭 卿,李亚栋.阴离子对构筑锌的肼配位卤族化合物的影响[J].无机化学学报,2004,20(7):819-823. |
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| 作者姓名： | 董亚杰 王如骥 彭 卿 李亚栋 |
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| 作者单位： | 清华大学化学系,原子分子纳米科学教育部重点实验室,北京,100084 |
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| 基金项目： | 国家自然科学基金(No.20025102、50028201、20151001)，全国优秀博士论文基金，国家重大基础研究发展规划“973”项目(No.G19990645-03)等多项基金资助项目。 |
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| 摘 要： | 采用含桥联双齿配体的过渡金属配合物来构筑多维无穷结构的研究是近年来晶体工程领域的一个热点。已经发现的结构有无穷链式、金刚石型、立方、梯式、蜂窝式、螺旋梯状与砖墙式等多种几何构型。其中一维无穷链式结构是最简单的一种构型，它不仅是理论模拟多维结构的最简模型，而且是构筑其他多维结构如分子梯式与二维层状结构的基元。
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| 关 键 词： | 阴离子 氢键 晶体结构 |
| 修稿时间： | 2003年10月22 |
The Stabilizing Effect of Anion on the Construction of Hydrozine Bridged Znic Halides Single Crystals |
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| DONG Ya-Jie,WANG Ru-Ji,PENG Qing and LI Ya-Dong.The Stabilizing Effect of Anion on the Construction of Hydrozine Bridged Znic Halides Single Crystals[J].Chinese Journal of Inorganic Chemistry,2004,20(7):819-823. |
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| Authors: | DONG Ya-Jie WANG Ru-Ji PENG Qing and LI Ya-Dong |
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| Institution: | Department of Chemistry, Tsinghua University, Beijing 100084,Department of Chemistry, Tsinghua University, Beijing 100084,Department of Chemistry, Tsinghua University, Beijing 100084 and Department of Chemistry, Tsinghua University, Beijing 100084 |
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| Abstract: | A series of hydrozine bridged metal halides single crystals were synthesized. Among them were Zn(N2H4)2F2]·2H2O and Zn(N2H4)2F]·Cl, the structures of which were characterized and shown to be 1D infinite chains. The crystal structures of the two compounds show that these 1D chains are organized into 3D structures through hydrogen bonds, and the halide anions play an important role in the stability of the crystals. The components and connecting types of these chains were compared with Zn(N2H4)2Cl2]·2H2O to illustrate the stabilizing effect of hydrogen bonds between one dimensional chains. CSD: 413707, 1; 413708, 2. |
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| Keywords: | anion hydrogen bond crystal structure |
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