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| 二维双层蜂窝状锌配合物的合成、晶体结构及性质研究 | |
| 引用本文： | 刘冬生,隋 岩,陈文通,黄长沧,陈建中.二维双层蜂窝状锌配合物的合成、晶体结构及性质研究[J].无机化学学报,2011,27(8):1607-1612. |
| 作者姓名： | 刘冬生 隋 岩 陈文通 黄长沧 陈建中 |
| 作者单位： | 1. 井冈山大学化学化工学院,江西省配位化学重点实验室,吉安343009;福州大学化学化工学院,福州 350108 2. 井冈山大学化学化工学院,江西省配位化学重点实验室,吉安343009 3. 福州大学化学化工学院,福州,350108 |
| 基金项目： | 国家自然科学基金(No.50772023); 井冈山大学自然科学研究项目(No.JZ10032,JZ0927)资助项目 |
| 摘 要： | 利用水热反应合成了一种新的二维双层蜂窝状锌配合物{Zn2(atz)3(N3)].H2O}n(1)(atz=5-氨基四氮唑),并用元素分析,红外光谱和X-射线单晶衍射对其结构进行了表征,该配合物属单斜晶系,C2/m空间群,晶胞参数为:a=1.0397(2)nm,b=1.7927(4)nm,c=1.109 2(2)nm,V=1.887 0(7)nm3,Z=4。该锌配合物是由N3-和原位合成的5-氨基四氮唑阴离子构成,拓扑分析表明该化合物显示出独特的4-连接六边形的蜂窝双层结构。同时还测定了该化合物的热稳定性及荧光性质。 |
| 关 键 词： | 锌配合物 5-氨基四氮唑 晶体结构 热稳定性 荧光性质 |
Synthesis, Crystal Structure and Properties of 2D Bilayer Honeycomb Network Zinc(Ⅱ) Complex |
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| LIU Dong-Sheng,SUI Yan,CHEN Wen-Tong,HUANG Chang-Cang and CHEN Jian-Zhong.Synthesis, Crystal Structure and Properties of 2D Bilayer Honeycomb Network Zinc(Ⅱ) Complex[J].Chinese Journal of Inorganic Chemistry,2011,27(8):1607-1612. | |
| Authors: | LIU Dong-Sheng SUI Yan CHEN Wen-Tong HUANG Chang-Cang and CHEN Jian-Zhong |
| Institution: | School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Jian, Jiangxi 343009, China; College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China,School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Jian, Jiangxi 343009, China,School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Jian, Jiangxi 343009, China,College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China and College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, China |
| Abstract: | A new 2D bilayer honeycomb zinc complex of {Zn2(atz)3(N3)]· H2O}n (1) (atz=5-amino-tetrazolate),hasbeen synthesized under the hydrothermal condition and characterized by elemental analysis,IR spectroscopy andsingle-crystal X-ray diffraction.The crystal structure of 1 is of monoclinic,space group C2/m with a=1.039 7(2)nm,b=1.7927(4) nm,c=1.1092(2) nm,V=1.8870(7) nm3,Z=4.Complex 1 is built from N3- anion and in-situgenerated 5-amino-tetrazolate ligand.The topological net of 1 shows a unique four-connected hexagonal bilayer“hcb” topology (honeycomb network).Thermal stability and luminescent property of the complex have also beeninvestigated.CCDC:722571. |
| Keywords: | zinc complex 5-amino-tetrazolate crystal structure thermal stability luminescent property |
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