| 3-羟基肉桂酸构筑的锌(Ⅱ)和镉(Ⅱ)配合物的合成、晶体结构和荧光性质 |
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| 引用本文： | 张春艳,傅君丹,温一航.3-羟基肉桂酸构筑的锌(Ⅱ)和镉(Ⅱ)配合物的合成、晶体结构和荧光性质[J].无机化学学报,2011,27(11):2308-2312. |
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| 作者姓名： | 张春艳 傅君丹 温一航 |
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| 作者单位： | 浙江师范大学物理化学研究所,浙江省固体表面反应化学重点实验室,金华321004 |
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| 基金项目： | 浙江师范大学博士启动资金 |
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| 摘 要： | 用水热法合成得到2个配合物，{ML2(bipy)(H2O)2]·2bipy}n(M=Cd 1，Zn 2；HL=3-羟基肉桂酸，bipy=4，4′-联吡啶)，并对它们进行了红外分析、元素分析，热重分析和单晶结构分析。配合物1和2为异质同晶，单斜晶系，P2/c空间群。中心金属M为六配位，相邻的MⅡ通过4，4′-联吡啶桥联形成沿b轴延伸的一维链状结构，此外还存在未配位的4，4′-联吡啶作为客体分子位于链与链之间。通过对配合物1和2的固态荧光测试表明，它们在绿光区均显示发光效应。
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| 关 键 词： | 3-羟基肉桂酸 4，4′-联吡啶 一维链状 荧光 |
Hydrothermal Syntheses, Crystal Structures and Luminescent Properties of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 3-Hydroxycinnamic Acid |
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| ZHANG Chun-Yan,FU Jun-Dan and WEN Yi-Hang.Hydrothermal Syntheses, Crystal Structures and Luminescent Properties of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 3-Hydroxycinnamic Acid[J].Chinese Journal of Inorganic Chemistry,2011,27(11):2308-2312. |
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| Authors: | ZHANG Chun-Yan FU Jun-Dan and WEN Yi-Hang |
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| Institution: | Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China |
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| Abstract: | Two linear structure metal-organic complexes,{ML2(bipy)(H2O)2]·2bipy}n (M=Cd 1; Zn 2),based on 3-hydroxycinnamic acid (HL) and 4,4′-bipyridine (bipy) were synthesized and characterized by IR,elemental analyses,thermogravimetric analyses and X-ray diffraction technique.Two complexes are isostructural crystallized in monoclinic system,P2/c space group.The center metal ion is six-coordinated by two nitrogen atoms from the bridging bipy ligands,two oxygen atoms from two L ligands,and two water molecules,forming a distorted octahedral geometry.The MⅡ ions and bipy ligands link each other to form a 1D linear chain that infinitely propagates along b axis,and discrete bipy as guest molecules intersperses between the chains.The luminescent properties in the solid state and thermogravimetric analyses (TGA) of two complexes are also discussed.CCDC:818712,1;818713,2. |
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| Keywords: | 3-hydroxycinnamic acid 4 4′-biphridine linear chain luminescent |
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