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噻吩甲酰基吡唑啉酮缩乙二胺配合物的合成、表征及生物活性
引用本文:于文锦,李锦州,李刚.噻吩甲酰基吡唑啉酮缩乙二胺配合物的合成、表征及生物活性[J].无机化学学报,1999,15(5):657-660.
作者姓名:于文锦  李锦州  李刚
作者单位:哈尔滨师范大学化学系,哈尔滨,150080
摘    要:A new ligand N,N′-bis[(1-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-2-thenoylmethylidyne]ethyl-enediimine (HPMTHP)2en and its five complexes have been sythesized. These complexes have the general formula [M(PMTHP)2en], where M=Cu(Ⅱ), Ni(Ⅱ)

关 键 词:酰基吡唑啉酮  双席夫碱  配合物  生物活性

SYNTHESIS, CHARACTERIZATION AND BIOACTIVITY OF COMPLEXES OF THENOYLPYRAZOLONE-ETHYLENEDIMINE
YU Wen-Jin,LI Jin-Zhou and LI Gang.SYNTHESIS, CHARACTERIZATION AND BIOACTIVITY OF COMPLEXES OF THENOYLPYRAZOLONE-ETHYLENEDIMINE[J].Chinese Journal of Inorganic Chemistry,1999,15(5):657-660.
Authors:YU Wen-Jin  LI Jin-Zhou and LI Gang
Institution:Department of Chemistry, Harbin Normal University, Harbin 150080,Department of Chemistry, Harbin Normal University, Harbin 150080 and Department of Chemistry, Harbin Normal University, Harbin 150080
Abstract:A new ligand N,N'-bis(1-phenyl-3-methyl-5-oxo-4-pyrazolinyl)-2-thenoylmethylidyne]ethyl-enediimine(HPMTHP)2en and its five complexes have been sythesized. These complexes have the general formula M(PMTHP)2en], where M=Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), Pd(Ⅱ), Pt(Ⅱ).They were characterized by elemental analysis, IR, UV-vis, magnetic moments and molar conductance. The results showed that the complexes are all of quadricoordinate square-planar geometry. The antibacterial experiment indicated that they have high antibacterial activities against S. aureus, B. subtillis, E.coli, E. carotovora, C. flaccumfaciens.
Keywords:acylpyrazolone      bis-schiff base      complex      bioactivity
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