| Cu(Ⅱ)-牛磺酸缩水杨醛席夫碱配合物的合成及晶体结构 |
| |
| 引用本文： | 张淑华,蒋毅民.Cu(Ⅱ)-牛磺酸缩水杨醛席夫碱配合物的合成及晶体结构[J].无机化学学报,2002,18(5):497-500. |
| |
| 作者姓名： | 张淑华 蒋毅民 |
| |
| 作者单位： | 广西师范大学化学化工系,桂林,541004 |
| |
| 摘 要： | The title complex was synthesized by reaction of taurine salicylic schiff base(TSSB), O-phenanthroline(phen) and cupric acetate in water-ethanol solution. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 498.00. And the crystal structure belongs to orthorhombic system with space group Pbcn and cell parameters: a=31.072(4)?, b=12.8909(18)?, c=10.3478(14)?; V=4144.7(10)?3,Z=8,Dc=1.596Mg·m-3,μ=1.197mm-1 and F(000)=2048. The compound is an one-dimensional chain complex of infinite length connecting with hydrogen bonds. The Cu(Ⅱ) was coordinated by two oxygen atoms and three nitrogen while the O atoms of Ac- groups did not coordinate. At the same time the Cu(Ⅱ)formed a distorted tragonal cone. Besides the capacities of coordination to Cu(Ⅱ) of atoms were discussed.
|
| 关 键 词： | 铜配合物 牛磺酸缩水杨醛席夫碱 晶体结构 |
| 修稿时间： | 2001年9月19日 |
Synthesis and Crystal Structure of [Cu(TSSB) (phen) ]·1.5H2O |
| |
| ZHANG Shu-Hua and JIANG Yi-Min.Synthesis and Crystal Structure of [Cu(TSSB) (phen) ]·1.5H2O[J].Chinese Journal of Inorganic Chemistry,2002,18(5):497-500. |
| |
| Authors: | ZHANG Shu-Hua and JIANG Yi-Min |
| |
| Institution: | Department of Chemistry, Guangxi Normal University, Guilin 541004 and Department of Chemistry, Guangxi Normal University, Guilin 541004 |
| |
| Abstract: | |
| |
| Keywords: | copper complex taurine-salicylic schiff base crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
