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纳米TiO2-ZnO复合材料的合成、结构与光催化性能
引用本文:丁士文,王利勇,张绍岩,刘淑娟,丁宇,刘燕朝,康全影.纳米TiO2-ZnO复合材料的合成、结构与光催化性能[J].无机化学学报,2003,19(6):631-635.
作者姓名:丁士文  王利勇  张绍岩  刘淑娟  丁宇  刘燕朝  康全影
作者单位:河北大学化学与环境科学学院,保定 071002,河北大学化学与环境科学学院,保定 071002,河北大学化学与环境科学学院,保定 071002,河北大学化学与环境科学学院,保定 071002,河北大学质监学院,保定 071002,河北大学化学与环境科学学院,保定 071002,河北大学化学与环境科学学院,保定 071002
基金项目:河北省自然科学基金资助项目(No.202104).
摘    要:Using ZnSO4 and TiCl4 as raw materials, nanometric TiO2-ZnO (ZnTiO3) is prepared at 180℃,0.8MPa by hydrothermal method. The effects of the reaction temperature and time on the nanometric TiO2-ZnO are also dis-cussed. XRD shows that the product is TiO2-ZnO (ZnTiO3) with noncrystal phase, and it changes to rhombic form above 870℃. TEM measurement indicates that the TiO2-ZnO is spherical particles, and the average diameter of the particles is 20nm. The UV light absorption properties are detected by UV spectrophotometer. The results show that the nanometric TiO2-ZnO has strong absorption at 200~370nm and at visible region. Photodegradation of dyes in an aqueous solution is investigated using nanometric TiO2-ZnO as a photocatalyst. The results show that after 60min illumination, the decolorization rate of the acidic red B and acidic black 234 dye can be arrived at 100%.

关 键 词:纳米复合氧化物  水热合成  光吸收性能  光催化
修稿时间:2002年11月20

Synthesis, Structure and Photocatalytic Property of Nano-TiO2-ZnO
DING Shi-Wen,WANG Li-Yong,ZHANG Shao-Yan,LIU Shu-Juan,DING Yu,LIU Yan-Chao and KANG Quan-Ying.Synthesis, Structure and Photocatalytic Property of Nano-TiO2-ZnO[J].Chinese Journal of Inorganic Chemistry,2003,19(6):631-635.
Authors:DING Shi-Wen  WANG Li-Yong  ZHANG Shao-Yan  LIU Shu-Juan  DING Yu  LIU Yan-Chao and KANG Quan-Ying
Abstract:
Keywords:nanometric TiO2-ZnO  hydrothermal synthesis  UV absorption  photocatalysis
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