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| 新的含有4-对甲基苯基-3，5-二(2-吡啶基)-1，2，4-三氮唑钴配合物的合成和晶体结构(英) | |
| 引用本文： | 朱敦如,王作祥,宋军,李一志,兰大艳.新的含有4-对甲基苯基-3，5-二(2-吡啶基)-1，2，4-三氮唑钴配合物的合成和晶体结构(英)[J].无机化学学报,2005,21(1):128-132. |
| 作者姓名： | 朱敦如 王作祥 宋军 李一志 兰大艳 |
| 作者单位： | 1. 南京工业大学化学系,南京,210009 2. 东南大学化学化工系,南京,210096 3. 南京大学配位化学国家重点实验室,配位化学研究所,南京,210093 |
| 基金项目： | 南京工业大学科研启动基金资助项目(No.51301031) |
| 摘 要： | A new cobalt(Ⅱ) complex, CoL2(NCS)2]·2CH2Cl2, L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21/c, a=0.867 40(17), b=1.453 9(3), c=1.781 9(4) nm, β=91.18(3)°, V=2.246 7(8) nm3 and Z=2. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. CCDC: 251658. |
| 关 键 词： | 钴配合物 晶体结构 三氮唑 |
| 收稿时间： | 2004/7/12 0:00:00 |
| 修稿时间： | 2004/11/4 0:00:00 |
Synthesis and Crystal Structure of a New Cobalt(Ⅱ) Complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole |
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| ZHU Dun-Ru,WANG Zuo-Xiang,SONG Jun,LI Yi-Zhi and LAN Da-Yan.Synthesis and Crystal Structure of a New Cobalt(Ⅱ) Complex with 4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)- 1,2,4-triazole[J].Chinese Journal of Inorganic Chemistry,2005,21(1):128-132. | |
| Authors: | ZHU Dun-Ru WANG Zuo-Xiang SONG Jun LI Yi-Zhi and LAN Da-Yan |
| Institution: | Department of Chemistry, Nanjing University of Technology, Nanjing 210009,Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096,Department of Chemistry, Nanjing University of Technology, Nanjing 210009,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096 |
| Abstract: | A new cobalt(Ⅱ) complex, CoL2(NCS)2]·2CH2Cl2, L=4-(p-methylphenyl)-3,5-bis(pyridin-2-yl)-1,2,4-triazole], was synthesized and its crystal structure was determined by X-ray analysis. The complex crystallizes in monoclinic system with space group P21 / c, a=0.867 40(17), b=1.453 9(3), c=1.781 9(4) nm,3=91.18(3)°, V=2.2467(8) nm3 and Z=2. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. CCDC: 251658. |
| Keywords: | cobalt(Ⅱ) complex crystal structure triazole |
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