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| 一种新型的T形一维镉配位聚合物[Cd(C5H4NCOO)·(C5H5NCOO)·(NO3)·(H2O)]n | |
| 引用本文： | 曾锡瑞,熊仁根,游效曾,S. Shanmuga Sundar Raj,Hoong-Kun Func.一种新型的T形一维镉配位聚合物[Cd(C5H4NCOO)·(C5H5NCOO)·(NO3)·(H2O)]n[J].无机化学学报,2000,16(4):641-646. |
| 作者姓名： | 曾锡瑞 熊仁根 游效曾 S. Shanmuga Sundar Raj Hoong-Kun Func |
| 作者单位： | 1. 南京大学配位化学研究所,配位化学国家重点实验室,南京210093;江西井冈山师范学院化学系,吉安343009 2. 南京大学配位化学研究所,配位化学国家重点实验室,南京210093 3. X-Ray Crystallography Unit, School of Physics, Universiti Sains Malaysis, 11800 Penang |
| 基金项目： | 国家教委回国人员启动基金 |
| 摘 要： | Cd(NO3)2· 6H2O和 4-(4-羧基吡啶 )氨基苯甲醛通过温和条件下的水热反应制备了一种新型的中性 T形一维链状配位聚合物，聚合 （异烟酸根）（ 4-羧酸根基吡啶铵）水合硝酸镉 ]。该配合物显示了蓝色荧光性质。 |
| 关 键 词： | 异烟酸根 一维镉配位聚合物 T形 荧光 |
| 收稿时间： | 2000/3/30 0:00:00 |
| 修稿时间： | 2000/6/10 0:00:00 |
A Novel T-shaped One-Dimensional Cadmium Coordination Polymer,[(Isonicotinato)(4-carboxylato-pyridinium)(nitrate)(aqua) cadmium]n |
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| ZENG Xi-Rui,XIONG Ren-Gen,YOU Xiao-Zeng,S. Shanmug Sundara-Rajc and Hoong-Kun Func.A Novel T-shaped One-Dimensional Cadmium Coordination Polymer,[(Isonicotinato)(4-carboxylato-pyridinium)(nitrate)(aqua) cadmium]n[J].Chinese Journal of Inorganic Chemistry,2000,16(4):641-646. | |
| Authors: | ZENG Xi-Rui XIONG Ren-Gen YOU Xiao-Zeng S Shanmug Sundara-Rajc and Hoong-Kun Func |
| Institution: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing university, Nanjing 210093;Chemistry Department, JingGangShan Normal College, Ji'an 343009,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing university, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing university, Nanjing 210093,X-Ray crystallography Unit, School of Physics, Universiti Sains Malaysis, 11800 Penang and X-Ray crystallography Unit, School of Physics, Universiti Sains Malaysis, 11800 Penang |
| Abstract: | A meso-hydrothermal reaction between Cd(NO3)2·6H2O and 4-(4′ -pyridylcarbonyl) amin-obenzaldehyde yields a novel neutral T-shaped one-dimensional chain coordination polymer (isonicotinato)(4-carboxylatopyridinium)(nitrate)(aqua)· cadmium(Ⅱ) ]n (Ⅰ) which displays blue fluorescent emission in the solid state. |
| Keywords: | isonicotinato cadmium one-dimension coordination polymer T-shaped fluorescence |
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