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Fe3O4/N-异丙烯酰胺(PNIPAM)纳米颗粒的合成
引用本文:仲 慧,张莉莉,张维光,王宝珠,朱玉兰.Fe3O4/N-异丙烯酰胺(PNIPAM)纳米颗粒的合成[J].无机化学学报,2007,23(8):1457-1462.
作者姓名:仲 慧  张莉莉  张维光  王宝珠  朱玉兰
作者单位:江苏省低维材料化学重点建设实验室,淮阴师范学院化学系,淮安,223300
基金项目:江苏省教育厅自然科学基金;江苏省自然科学基金
摘    要:A magnetic and thermosensitive poly(N-isopropylacrylamide)(PNIPAM) nanoparticles were prepared by the following procedure. The core-shell composite microparticles were synthesized by precipitating polymerization with Fe3O4 being entrapped with SiO2 as core and cross-linked PNIPAM as shell. Then, the SiO2 core was etched by hydrofluoric acid and magnetic thermosensitive Fe3O4/PNIPAM particles were formed. It has also been shown that the Fe3O4/PNIPAM nanoparticles are featured by lower critical solution temperature (LCST) at 33.0 ℃ while the temperature varies from 28.0 ℃ to 36.0 ℃. The composite magnetic thermosensitive particles were characterized by XRD, SEM, TEM and FTIR. The synthetic mechanism is also discussed.

关 键 词:温敏    核壳    纳米颗粒    磁性物质
文章编号:1001-4861(2007)08-1457-06
修稿时间:2007-03-112007-06-26

Synthesis of Fe3O4/Poly(N-isopropylacrylamide)(PNIPAM) Nanoparticles
ZHONG Hui,ZHANG Li-Li,ZHANG Wei-Guang,WANG Bao-Zhu and ZHU Yu-Lan.Synthesis of Fe3O4/Poly(N-isopropylacrylamide)(PNIPAM) Nanoparticles[J].Chinese Journal of Inorganic Chemistry,2007,23(8):1457-1462.
Authors:ZHONG Hui  ZHANG Li-Li  ZHANG Wei-Guang  WANG Bao-Zhu and ZHU Yu-Lan
Institution:Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, Deprtment of Chemistry, Huaiyin Teachers College, Huaian, Jiangsu 223300
Abstract:
Keywords:thermosenitive  core-shell  nanoparticles  magnetic material
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