| 4-羧基苯氧乙酸锰配位聚合物[Mn(p-CPOA)(H2O)3]n的合成与晶体结构 |
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| 引用本文： | 谷长生,高 山,霍丽华,朱志彪,赵 辉,赵经贵.4-羧基苯氧乙酸锰配位聚合物[Mn(p-CPOA)(H2O)3]n的合成与晶体结构[J].无机化学学报,2004,20(7):853-856. |
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| 作者姓名： | 谷长生 高 山 霍丽华 朱志彪 赵 辉 赵经贵 |
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| 作者单位： | 黑龙江大学化学化工学院，哈尔滨 150080,黑龙江大学化学化工学院，哈尔滨 150080,黑龙江大学化学化工学院，哈尔滨 150080,黑龙江大学化学化工学院，哈尔滨 150080,黑龙江大学化学化工学院，哈尔滨 150080,黑龙江大学化学化工学院，哈尔滨 150080 |
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| 基金项目： | 国家自然科学基金(No.20101003)，黑龙江省自然科学基金(No.B0007)，黑龙江省海外学人重点基金(No.1053HZ002)资助项目。 |
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| 摘 要： | The coordination polymer of Mn(p-CPOA)(H2O)3]n (p-CPOA=4-carboxylphenoxyacetate) was synthesized and characterized by elemental analysis, IR， X-ray single crystal diffraction. The title complex crystallizes in mono-clinic with space group P21/c, a=0.699 8(1) nm, b=1.6235(3) nm, c=1.014 3(2) nm, β=99.55(3)°. V=1.136 5(4) nm3, Z=4, Dc=1.772 g·cm-3, μ=1.193mm-1, F(000)=620, R=0.026 8, wR=0.074 5. The manganese atom is seven-coordinate involving four oxygen atoms of different p-CPOA2- ligands and three coordinated water, forming a distorted pentagonal bipyramindal environment. Two manganese atoms are bridged by p-CPOA2- ligand, forming a one-dimensional zigzag chain structure along p axis. The adjacent distance of Mn…Mn atoms is 1.021 0 nm. The three-dimensional hydrogen bonding network was formed by the intermolecular hydrogen bonds. CCDC: 219358.
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| 关 键 词： | 锰(Ⅱ)羧酸配合物 合成 晶体结构 |
| 修稿时间： | 2003年11月10 |
Synthesis, Crystal Structure of Coordination Polymer [Mn(p-CPOA)(H2O)3]n with 4-carboxylphenoxyacetic Acid Ligand |
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| GU Chang-Sheng,GAO Shan,HUO Li-Hu,ZHU Zhi-Biao,ZHAO Hui and ZHAO Jing-Gui.Synthesis, Crystal Structure of Coordination Polymer [Mn(p-CPOA)(H2O)3]n with 4-carboxylphenoxyacetic Acid Ligand[J].Chinese Journal of Inorganic Chemistry,2004,20(7):853-856. |
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| Authors: | GU Chang-Sheng GAO Shan HUO Li-Hu ZHU Zhi-Biao ZHAO Hui and ZHAO Jing-Gui |
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| Institution: | College of Chemistry and Chemical Technology, HeilongJiang University, Harbin 150080,College of Chemistry and Chemical Technology, HeilongJiang University, Harbin 150080,College of Chemistry and Chemical Technology, HeilongJiang University, Harbin 150080,College of Chemistry and Chemical Technology, HeilongJiang University, Harbin 150080,College of Chemistry and Chemical Technology, HeilongJiang University, Harbin 150080 and College of Chemistry and Chemical Technology, HeilongJiang University, Harbin 150080 |
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| Abstract: | |
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| Keywords: | carboxylate manganese(II) complex synthesis crystal structure |
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