| 荧光材料GdOCl∶Er~(3+),Yb~(3+)的深红-近红外发光研究 |
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| 引用本文： | 邵黎明,荆西平.荧光材料GdOCl∶Er~(3+),Yb~(3+)的深红-近红外发光研究[J].无机化学学报,2014,30(10):2295-2300. |
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| 作者姓名： | 邵黎明 荆西平 |
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| 作者单位： | 1. 中国石油勘探开发研究院,北京 100083 ;北京大学化学与分子工程学院,北京 1000871
2. 北京大学化学与分子工程学院,北京,1000871 |
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| 基金项目： | 国家自然科学基金（No.20821091，20423005）以及国家重点基础研究发展计划（No.2009CB939901）资助项目。 |
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| 摘 要： | 采用高温固相合成法制备了Er3+,Yb3+双掺杂的GdOCl荧光材料,并研究其荧光性能。该双掺杂体系荧光粉吸收紫外光,发出红色(619 nm)和近红外(~979 nm)荧光。在这些荧光材料中,1个Er3+离子可以有效将其能量转移给2个Yb3+离子。通过改变Yb3+掺杂浓度,对比Gd0.998 5-yOCl∶0.0015Er3+,yYb3+中的Er3+的发射光谱和不同检测波长的荧光寿命变化特点,对Er3+-Yb3+发生量子剪裁的能级进行分析和指认,并计算了能量转化效率(η)和量子效率(Q)。正是由于具备这种荧光性能,该荧光材料体系有望在荧光太阳能收集器以及军事和医学的红外显示和探测技术中获得应用。
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| 关 键 词： | 量子剪裁 GdOCl 稀土离子 红色和近红外荧光 |
| 收稿时间： | 4/1/2014 12:00:00 AM |
| 修稿时间： | 5/7/2014 12:00:00 AM |
Red and Near-Infrared Quantum Cutting Luminescence of Er3+,Yb3+-Codoped GdOCl Phosphor |
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| SHAO Li-Ming and JING Xi-Ping.Red and Near-Infrared Quantum Cutting Luminescence of Er3+,Yb3+-Codoped GdOCl Phosphor[J].Chinese Journal of Inorganic Chemistry,2014,30(10):2295-2300. |
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| Authors: | SHAO Li-Ming and JING Xi-Ping |
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| Institution: | Research Institute of Petroleum Exploration & Development (RIPED), Petro China, Beijing 100083, China;Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry & Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry & Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China |
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| Abstract: | The phosphors in the system GdOCl:Er3+,Yb3+ were synthesized by solid-state reactions and their photoluminescence properties were investigated. These phosphors have absorption in the ultraviolet light region and give luminescence in the red (619 nm) and near-infrared region (~979 nm). In these phosphors, one Er3+ ion can effectively transfer its absorbed energy to two Yb3+ ions, which are suitable for the application in the device of luminescent solar concentrator (LSC) and near-infrared display. |
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| Keywords: | quantum cutting GdOCl rare earths red and near-infrared luminescence |
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