| Interaction and Interfacial Molecular Recognition of Calix[4] arene Derivatives Bearing Nucleobases for Complementary Nucleoside |
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| 作者姓名： | 王震生 陆国元 盛欣 郭勋 金传明 |
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| 作者单位： | DepartmentofChemistry,NanjingUniversity,Nanjing,Jiangsu210093,China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChinaandtheAnalyticalCenterofNanjingUniversity |
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| 摘 要： | The p-tert-butyl calix4] arene derivatives la with uracils and 1b with adenines at the lower rim were synthesized.The Interaction between 1a and 1b in CDCl3 solution was demonstrated by ^1H NMR spectra.The interfacial molecular recognitions of la and 1b for the complementary nucleosides in aqueous subphases were investigated by Langmuir-Blodgett technique.
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| 关 键 词： | 分子相互作用 杯[4]芳烃衍生物 合成 氢气粘合 核酸基 核苷 嘧啶 嘌呤 |
Interaction and Interfacial Molecular Recognition of Calix[4]arene Derivatives Bearing Nucleobases for Complementary Nucleoside |
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| Wang Zhen‐Sheng,Lu Guo‐Yuan,Sheng Xin,Guo Xun,Jin Chuan‐Ming.Interaction and Interfacial Molecular Recognition of Calix[4] arene Derivatives Bearing Nucleobases for Complementary Nucleoside[J].Chinese Journal of Chemistry,2003,21(6):600-603. |
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| Authors: | Wang Zhen‐Sheng Lu Guo‐Yuan Sheng Xin Guo Xun Jin Chuan‐Ming |
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| Abstract: | The p tert butyl calixarene derivatives 1a with uracils and 1b with adenines at the lower rim were synthesized. The Interaction between 1a and 1b in CDCl 3 solution was demonstrated by 1H NMR spectra. The interfacial molecular recognitions of 1a and 1b for the complementary nucleosides in aqueous subphases were investigated by Langmuir Blodgett technique. |
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| Keywords: | calixarene molecular recognition hydrogen bonding nucleoside Langmuir Blodgett film |
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