| One-pot Synthesis of Isoxazolines Using Soluble Polymer-supported Acrylate |
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| 作者姓名： | 商永嘉 王彦广 |
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| 作者单位： | [1]CollegeofChemistryandMaterialScience,AnhuiNormaluniversity,Wuhu,Anhui241000,China [2]DepartmentofChemistry,ZhejiangUniversity,Hangzhou,Zhejiang310027,China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 9972 0 37) |
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| 摘 要： | An eficient liquid-phase synthesis of isoxazolines through a 1,3-dipolar cycloaddition is described.Soluble polymer-supported acrylate reacted with nitrile oxides generated in-situ,followed by cleavage from the support giving corresponding isoxazolines in high yields and excellent purities.
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| 关 键 词： | 异噁唑碱 合成 液相法 丙烯酸盐 环加成反应 聚乙烯甘醇 PEG |
One-pot Synthesis of Isoxazolines Using Soluble Polymer-supported Acrylate |
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| SHANG,Yong-Jia a,b WANG,Yan-Guang a.One-pot Synthesis of Isoxazolines Using Soluble Polymer-supported Acrylate[J].Chinese Journal of Chemistry,2003,21(1):7-8. |
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| Authors: | SHANG Yong-Jia a b WANG Yan-Guang a |
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| Institution: | SHANG,Yong-Jia a,b WANG,Yan-Guang a Department of Chemistry,Zhejiang University,Hangzhou,Zhejiang 310027,China b College of Chemistry and Material Science,Anhui Normal University,Wuhu,Anhui 241000,China |
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| Abstract: | An efficient liquid-phase synthesis of isoxazolines through a 1,3-dipolar cycloaddition is described. Soluble polymer-supported acrylate reacted with nitrile oxides generated in-situ, followed by cleavage from the support giving corresponding isoxazolines in high yields and excellent purities. |
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| Keywords: | poly(ethylene glycol) (PEG) isoxazoline cycloaddition liquid-phase |
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