| Characterization and Dehydrogenation Activity of SBA-15 and HMS Supported Chromia Catalysts |
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| 作者姓名： | 乐洪咏 郑波 乐英红 张雪峥 华伟明 高滋 |
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| 作者单位： | YUE，Hong-Yong ZHENG，Bo YUE，Ying-Hong ZHANG，Xue-Zheng HUA，Wei-Ming GAO，ZiLaboratory of Molecular Catalysis and Innovative Materials，Department of Chemistry，Fudan University，Shanghai 200433，China |
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| 基金项目： | theMajorStateBasicResearchDevelopmentProgramofChina (No .G2 0 0 0 0 775 0 0 )andtheFoundationforUniversityKeyTeachersbytheEducationMinistryofChina |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＥｎｏｒｍｏｕｓｓｔｕｄｙｈａｓｂｅｅｎｄｅｖｏｔｅｄｔｏＭ4 1Ｓ ,ｔｈｅｆｉｒｓｔｆａｍｉｌｙｏｆｍｅｓｏｐｏｒｏｕｓｍｏｌｅｃｕｌａｒｓｉｅｖｅｓｒｅｐｏｒｔｅｄｉｎ1992 ,1,2 ｉｎｃｌｕｄｉｎｇｔｈｅｉｒｍｏｄｉｆｉｃａｔｉｏｎｓａｎｄａｐｐｌｉｃａｔｉｏｎｓｉｎｃａｔａｌｙｓｉｓ .Ｔｈｅａｔｔｒａｃｔｉｖｅｐｒｏｐｅｒｔｉｅｓｏｆｔｈｅｓｅｍａｔｅｒｉａｌｓａｒｅｔｈｅｉｒｈｉｇｈｓｐｅｃｉｆｉｃｓｕｒｆａｃｅａｒｅａ (>10 0 0ｍ2 /ｇ) ,ｗｅｌｌ ｄｅ ｆｉｎｅｄｓｔｒ…
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Characterization and Dehydrogenation Activity of SBA-15 and HMS Supported Chromia Catalysts |
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| YUE,Hong-Yong ZHENG,Bo YUE,Ying-Hong ZHANG,Xue-Zheng HUA,Wei-Ming GAO,ZiLaboratory of Molecular Catalysis and Innovative Materials.Characterization and Dehydrogenation Activity of SBA-15 and HMS Supported Chromia Catalysts[J].Chinese Journal of Chemistry,2002,20(11):1192-1198. |
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| Authors: | YUE Hong-Yong ZHENG Bo YUE Ying-Hong ZHANG Xue-Zheng HUA Wei-Ming GAO ZiLaboratory of Molecular Catalysis and Innovative Materials |
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| Institution: | YUE,Hong-Yong ZHENG,Bo YUE,Ying-Hong ZHANG,Xue-Zheng HUA,Wei-Ming GAO,ZiLaboratory of Molecular Catalysis and Innovative Materials,Department of Chemistry,Fudan University,Shanghai 200433,China |
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| Abstract: | SBA‐15 and HMS supported chromia catalysts were prepared and characterized. Chromia is highly dispersed on the mesoporous supports when its loading is 7 wt%. The supported catalysts display high activity, selectivity and stability for dehydrogenation of ethylbenzene and propane. ESR measurement of the catalysts before and after reaction shows that the active species for dehydrogenation reaction might be Cr3+ species on the catalyst surface, and the activity of the catalyst is probably correlated with the dispersion of Cr3+ species. |
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| Keywords: | SBA-15 HMS supported chromia catalyst ethylbenzene dehydrogenation propane dehydrogenation |
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