Samarium mediated pinacol coupling of carbonyl compounds in the presence of a catalytic amount of iodine under aqueous media |
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| Authors: | WANG Lei ZHANG Yong-Min |
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| Institution: | WANG,Lei ZHANG,Yong-Min
Department of Chemistry,Zhejiang University at Xixi Campus,Hangzhou,Zhejiang 310028,China |
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| Abstract: | In the presence of a catalytic amount of iodine, metallic samarium mediated pinacol coupling of carbonyl compounds has been carried out under saturated aqueous NH4Cl-THF conditions at room temperature. It gives corresponding 1,2-diols in good yields. |
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| Keywords: | Samarium iodine pinacol coupling aqueous media |
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