| Syntheses and Crystal Structure of a New 3D Ag(I)-Fumaric Acid Framework, [Ag(hmt)(fma)_(1/2)·2H_2O]_n |
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| 引用本文： | 毕文华,孙道峰,曹荣,李星,时茜,洪茂椿.Syntheses and Crystal Structure of a New 3D Ag(I)-Fumaric Acid Framework, [Ag(hmt)(fma)_(1/2)·2H_2O]_n[J].中国化学,2003,21(6):655-658. |
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| 作者姓名： | 毕文华 孙道峰 曹荣 李星 时茜 洪茂椿 |
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| 作者单位： | State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou，Fujian 350002，China |
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| 基金项目： | ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 990 10 0 5 ) |
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| 摘 要： | IntroductionInrecentseveraldecades ,thedesignandsynthesesofnovelstructurematerialhavebecomeanactiveresearchfield .1 3However,thedeliberatedesignofnewfunctionalmaterialsbasedonpolymerisstillanarduouschallengetoinorganicchemistsbecausetheassemblyofthosestructuresisheavilyinfluencedbymanyfactorssuchasthepHval ue ,thesolventandcounterion .4 Muchefforthasbeende votedtoexploreusefulsyntheticstrategiesinordertoob taintheanticipatoryframework .Fortunately ,alotofin triguingstructureshavebeensynthesiz…
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Syntheses and Crystal Structure of a New 3D Ag (I)‐Fumaric Acid Framework, [Ag (hmt) (fma)1/2 · 2H2O]n |
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| Bi Wen‐Hua,Sun Dao‐Feng,Cao Rong,Li Xing,Shi Qian,Hong Mao‐Chun.Syntheses and Crystal Structure of a New 3D Ag (I)‐Fumaric Acid Framework, [Ag (hmt) (fma)1/2 · 2H2O]n[J].Chinese Journal of Chemistry,2003,21(6):655-658. |
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| Authors: | Bi Wen‐Hua Sun Dao‐Feng Cao Rong Li Xing Shi Qian Hong Mao‐Chun |
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| Abstract: | A new silver (I) coordination polymer, Ag(hmt) (fma)1/2 · 2H2O]n (1), (hmt = hexamethylenetetramine, fma = furmaric acid), was obtained by self‐assembly of hmt, fma and AgNO3 in the mixed solvent of methanol, dichloromethane and water (CH3OH:CH2Cl2:H2O = 5:5:1), and characterized by X‐ray diffraction analysis. Complex 1 belongs to orthorhombic space group Pbcn with cell parameters a = 1.72043(5) nm, b=1.19704(2) nm, c = 1.11685(3) nm, V = 2.30007(10) nm3, Z = 8, CCDC number: 194381. In complex 1, each hmt ligand acts as a μ3‐bridge to link three Ag(I) atoms and in turn every Ag(I) ion attaches to three hmt ligands to produce a 2D honeycomb network, which is further linked by the bidentate fma ligands to form a 3D noninterpenetrating open framework with one‐dimensional channels being filled by guest molecules. |
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| Keywords: | fumaric acid silver polymer honeycomb layer crystal structure |
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