| A Triple Cluster Platinaborane：[（P（2）Ph3）Pt（1）（μ2—B（11）—B（9）—OC（CH3）3—B10H10））Pt（7）（P（1）Ph3）]2 |
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| 引用本文： | 胡春华,孙杰,等.A Triple Cluster Platinaborane：[（P（2）Ph3）Pt（1）（μ2—B（11）—B（9）—OC（CH3）3—B10H10））Pt（7）（P（1）Ph3）]2[J].中国化学,2002,20(6):536-538. |
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| 作者姓名： | 胡春华 孙杰 |
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| 作者单位： | [1]ResearchCenterofAnalysisandMeasurement,FudanUniversity,Shanghai200433,China [2]ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China |
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| 基金项目： | theNationalNaturalScienceFoundationofChina (No.2 98730 0 9) |
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| 摘 要： | Ｉｎｒｅｃｅｎｔｙｅａｒｓｓｙｎｔｈｅｓｉｓａｎｄｃｈａｒａｃｔｅｒｉｚａｔｉｏｎｏｆｎｅｗｍｅｔａｌｌａｂｏｒａｎｅｓａｎｄｍｅｔａｌｌａｃａｒｂｏｒａｎｅｓｈａｖｅａｔｔｒａｃｔｅｄｍｕｃｈｉｎｔｅｒｅｓｔ .1 3Ａｗｉｄｅｖａｒｉｅｔｙｏｆｃｌｕｓｔｅｒｃｏｍｐｌｅｘｅｓ ,ｉｎｗｈｉｃｈｃｏｏｒｄｉｎａｔｉｏｎｃａｎｂｅｖｉａＢ—Ｈ—Ｍｏｒ (ａｎｄ)Ｂｎ—Ｍｂｏｎｄ(ｎ =1,2 ,3,4 ,5 ,6 ) ,ｈａｖｅｂｅｅｎｓｙｎｔｈｅｓｉｚｅｄａｎｄｓｔｒｕｃｔｕｒａｌｌｙｃｈａｒａｃｔｅｒｉｚｅｄ .Ｔｈｅｐｏ…
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| 关 键 词： | 三元配合物 铂 甲硼烷 金属甲硼烷 结构 合成 |
A Triple Cluster Platinaborane: [(P(2)Ph3)Pt(1)(μ2‐B(11)‐(B(9)‐OC(CH3)3‐B10H10))Pt(7)(P(1)Ph3)]2 |
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| HU,Chun Hua YONG,Wei DOU,Jian Min SUN,Jie HU,Ke Ji JIN,Ruo Shui ZHENG,Pei Ju a Research Center of Analysis and Measurement,Fudan University,Shanghai ,China b.A Triple Cluster Platinaborane: [(P(2)Ph3)Pt(1)(μ2‐B(11)‐(B(9)‐OC(CH3)3‐B10H10))Pt(7)(P(1)Ph3)]2[J].Chinese Journal of Chemistry,2002,20(6):536-538. |
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| Authors: | HU Chun Hua YONG Wei DOU Jian Min SUN Jie HU Ke Ji JIN Ruo Shui ZHENG Pei Ju a Research Center of Analysis and Measurement Fudan University Shanghai China b |
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| Institution: | HU,Chun Hua YONG,Wei DOU,Jian Min SUN,Jie HU,Ke Ji JIN,Ruo Shui ZHENG,Pei Ju a Research Center of Analysis and Measurement,Fudan University,Shanghai 200433,China b Shanghai Institute of Organic Chemistry,Chinese Aca |
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| Abstract: | The title platinaborane, (P(2)Ph3)Pt(l)(μ2‐B(11)‐(B(9)‐OC‐(CH3)3‐B10H10)Pt(7)(P(1)Ph3)]2, a triple cluster, which is a binuclear Pt complex dimmer, was prepared. Single crystal X‐ray diffraction analysis shows that a Pt(7) atom served as a common vertex between cluster |PtB10| and |Pt4|. The |Pt4| cluster is of parallelogram. |
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| Keywords: | platinaborane metallaborane triple cluster |
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