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Studies on Properties of p-Nitrophenylazo Calixarene Derivatives
作者姓名:金传明  归敏芝  陆国元  郭勋  张宏  游效曾
作者单位:Department of Chemistry,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210093,China,National Laboratory of Molecular and Biomolecular Electronics,Southeast University,Nanjing,Jiangsu 210096,China,Department of Chemistry,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210093,China,Department of Chemistry,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210093,China,National Laboratory of Molecular and Biomolecular Electronics,Southeast University,Nanjing,Jiangsu 210096,China,Department of Chemistry,State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing,Jiangsu 210093,China Department of Chemistry and Environment Engineering,Hubei Normal University,Huangshi,Hubei 435002,China
基金项目:ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .90 10 10 18)andtheCenterofMaterialsAnalysisofNanjingUniver sity .
摘    要:Organiccompoundswithsecond ordernonlinearoptical(NLO)propertieshavevariouspotentialinthedevelopmentofmaterialsforapplicationssuchasfrequencydoublingandop ticalswitching .1,2 TraditionalorganicNLOmaterialsareor ganicmoleculesthatcontainelectron donatingandelectron acceptinggroupsconnectedviaaconjugatedπsystem ,i.e .,socalledD π Astructure .Generally ,thesecond ordernon linearhyperpolarizability βofamoleculeincreaseswithin creasinglengthoftheconjugatedπsystemandincreasingstrengthofthedono…


Studies on Properties of p-Nitrophenylazo Calixarene Derivatives
Abstract:
Keywords:calixarene  NLO property  crystal structure  conformation  LB film  
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