| A Two-coordinate Copper(I) Complex Constructed from Cyanuric acid and 4,4′-bipyridyl: Synthesis, Structure and Photoluminescence |
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| 引用本文： | 岳琦,杨进,袁宏明,陈接胜.A Two-coordinate Copper(I) Complex Constructed from Cyanuric acid and 4,4′-bipyridyl: Synthesis, Structure and Photoluminescence[J].中国化学,2006,24(8):1045-1049. |
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| 作者姓名： | 岳琦 杨进 袁宏明 陈接胜 |
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| 作者单位： | State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, Jilin 130012, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China（No. 20331010）. |
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| 摘 要： | A two-coordinate copper（Ⅰ） complex, Cu2（bipy）（H2L）2 （1） （H3L=cyanuric acid, bipy=4,4＇-bipyridyl）, which exhibits strong photoluminescence, has been synthesized under hydrothermal conditions and structurally characterized by single crystal X-ray diffraction. The compound crystallizes in the monoclinic space group P21/n, with cell parameters： Mr= 539.42, a= 13.4806（5）A↑°, b=4.5234（2） A↑°, c= 15.4952（8）A↑°,β = 105.526（3）°, V=910.39（7）A↑°^3, Z=2 and μ=3.52 mm^ -1. In the structure the two Cu（Ⅰ） ions are bridged by bipy to form a two-coordinate copper（Ⅰ） dimer. The adjacent dimer units are connected by hydrogen bonding interactions, resulting in 1D zigzag chains along the c axis. 1 emits intense yellow light when excited with UV light.
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| 关 键 词： | 二价铜（Ⅰ）配合物 氰尿酸 4 4＇-二吡啶 合成 结构分析 光致发光 |
| 收稿时间： | 2005-03-28 |
| 修稿时间： | 2005-03-282006-04-03 |
A Two‐coordinate Copper(I) Complex Constructed from Cyanuric Acid and 4,4′‐Bipyridyl: Synthesis,Structure and Photoluminescence |
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| YUE Qi, YANG Jin, YUAN Hong-Ming, CHEN Jie-Sheng.A Two‐coordinate Copper(I) Complex Constructed from Cyanuric Acid and 4,4′‐Bipyridyl: Synthesis,Structure and Photoluminescence[J].Chinese Journal of Chemistry,2006,24(8):1045-1049. |
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| Authors: | YUE Qi YANG Jin YUAN Hong-Ming CHEN Jie-Sheng |
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| Abstract: | A two‐coordinate copper(I) complex, Cu2(bipy)(H2L)2 ( 1 ) (H3L=cyanuric acid, bipy=4,4′‐bipyridyl), which exhibits strong photoluminescence, has been synthesized under hydrothermal conditions and structurally characterized by single crystal X‐ray diffraction. The compound crystallizes in the monoclinic space group P21/n, with cell parameters:Mr=539.42, a=13.4806(5) Å, b=4.5234(2) Å, c=15.4952(8) Å, β=105.526(3)°, V=910.39(7) Å3,Z=2 and μ=3.52 mm?1. In the structure the two Cu(I) ions are bridged by bipy to form a two‐coordinate copper(I) dimer. The adjacent dimer units are connected by hydrogen bonding interactions, resulting in 1D zigzag chains along the c axis. 1 emits intense yellow light when excited with UV light. |
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| Keywords: | copper(I) complex photoluminescence cyanuric acid 4 4′‐bipyridyl |
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