Synthesis and Properties of a Novel 3D Europium Coordination Polymer with Helical Chain and (3,6)‐Connected rtl Net |
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| Authors: | Zhifeng Liu Bowen Lai Huiliang Wen Julianne Robbins Nei Huang |
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| Institution: | 1. State Key Laboratory of Food Science and Technology, Nanchang University, Nanchang, Jiangxi 330047, China;2. Chemicals Analysis Department, Nanchang Institute for Food and Drug Control, Nanchang, Jiangxi 330038, China;3. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia, 30332, United States;4. Jiangxi Sinograin Quality Supervision Center, Nanchang, Jiangxi 330000, China |
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| Abstract: | The first coordination polymer of 2,2′‐((4‐carboxymethyl‐1,3‐phenylene)bis(oxy)) diacetic acid (H3L) with europium(III) ion, Eu(L)(H2O)]·3H2O ( 1 ), has been hydrothermally synthesized and structurally characterized. Complex 1 exhibits a 3D coordination polymer with helical chain and rtl topology of the point symbol (4·62)2(42·610·83) based on Eu2(COO)4] as secondary building unit (SBU). Furthermore, the luminescent and magnetic properties of complex 1 are studied. |
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| Keywords: | europium coordination polymer helix topological structure luminescence magnetism |
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