| 一种经MCM-41负载双齿膦钯(0)配合物催化的羰基化Suzuki偶联合成二芳酮的新途径 |
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| 引用本文： | 郑国民a 王萍萍a,b,蔡明中,a.一种经MCM-41负载双齿膦钯(0)配合物催化的羰基化Suzuki偶联合成二芳酮的新途径[J].中国化学,2009,27(7):1420-1426. |
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| 作者姓名： | 郑国民a 王萍萍a b 蔡明中 a |
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| 作者单位： | a 江西师范大学化学化工学院，南昌，江西330022 ;;b 九江学院化学系, 九江，江西332000 ; |
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| 摘 要： | 在催化量的MCM-41负载双齿膦钯(0)配合物存在下，芳基碘化物和芳基硼酸、一氧化碳在常压下能顺利进行羰基化Suzuki偶联反应，高产率地生成了各种二芳酮化合物。MCM-41负载双齿膦钯(0)配合物具有比PdCl2(PPh3)2 更高的活性和选择性，且可回收再用10次其活性基本不变，为各种功能化二芳酮的合成提供了方便实用的新途径。
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| 关 键 词： | 羰基化Suzuki偶联 双齿膦钯(0)配合物 MCM-41 二芳酮 杂相催化 |
| 收稿时间： | 2009-1-18 |
| 修稿时间： | 2009-3-17 |
A New Route to Biaryl Ketones via Carbonylative Suzuki Coupling Catalyzed by MCM‐41‐supported Bidentate Phosphine Palladium(0) Complex |
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| Guomin ZHENG,Pingping WANG,Mingzhong CAI.A New Route to Biaryl Ketones via Carbonylative Suzuki Coupling Catalyzed by MCM‐41‐supported Bidentate Phosphine Palladium(0) Complex[J].Chinese Journal of Chemistry,2009,27(7):1420-1426. |
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| Authors: | Guomin ZHENG Pingping WANG Mingzhong CAI |
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| Institution: | 1. Department of Chemistry, Jiangxi Normal University, Nanchang, Jiangxi 330022, China;2. Department of Chemistry, Jiujiang College, Jiujiang, Jiangxi 332000, China |
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| Abstract: | A variety of biaryl ketones can be conveniently synthesized in good to high yields via the first heterogeneous carbonylative Suzuki coupling of arylboronic acids with aryl iodides under atmospheric pressure of carbon monoxide in the presence of a catalytic amount of MCM‐41‐supported bidentate phosphine palladium(0) complex MCM‐41‐2P‐Pd(0)]. This polymeric palladium catalyst can be reused at least 10 times without any decrease in activity. |
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| Keywords: | carbonylative Suzuki coupling bidentate phosphine palladium(0) complex MCM‐41 biaryl ketone heterogeneous catalysis |
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