| 铋(Ⅲ)配合物Bi(1,10-phen)[S2CN(CH3)2]2(NO3), |
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| 引用本文： | 尹汉东,王传华,邢秋菊.铋(Ⅲ)配合物Bi(1,10-phen)[S2CN(CH3)2]2(NO3),[J].中国化学,2005,23(12):1631-1636. |
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| 作者姓名： | 尹汉东 王传华 邢秋菊 |
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| 作者单位： | Department of Chemistry, Liaocheng University, Liaocheng, Shandong 252059, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No. 20271025）, the Natural Science Foundation of Shandong Province （No. L2003B01）. |
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| 摘 要： | Three bismuth（Ⅲ） complexes Bi（1,10-phen）S2CN（CH3）2]2（NO3） （1）, {Bi（S2COCH3）S2CNC6Hs（CH3）]2}2 （2） and Bi（S2CNBu2）2（CH3OH）（NO3）]∞ （3） were synthesized and characterized by elemental analysis and IR spectra. Their crystal structures were determined by X-ray single crystal diffraction analysis. Studies show that complex 1 has a monomeric structure with the central bismuth atom eight-coordinated in a capped distorted pentagonal bipyramidal geometry. The complex 2 takes centrosymmetric dimeric structure and the bismuth atoms are seven-coordinated in distorted pentagonal bipyramidal geometry.In complex 3, the bismuth atoms are seven-coordinated in distorted pentagonal bipyramidal geometry by bridging nitrate O atoms and the resulting structure is onedimensional infinite chain polymer.
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| 关 键 词： | 铋 二硫代氨基甲酸盐 黄酸盐 晶体结构 合成方法 |
| 收稿时间： | 2004-11-30 |
| 修稿时间： | 2004-11-302005-08-30 |
Synthesis and Crystal Structure of Bismuth(III) Complexes Bi(1,10‐phen)[S2CN(CH3)2]2(NO3), {Bi(S2COCH2)[S2CNC6H5(CH3)]2}2 and [Bi(S2CNBu2)2(CH3OH)(NO3)]∞ |
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| YIN Han-Dong, WANG Chuan-Hua, XING Qiu-Ju.Synthesis and Crystal Structure of Bismuth(III) Complexes Bi(1,10‐phen)[S2CN(CH3)2]2(NO3), {Bi(S2COCH2)[S2CNC6H5(CH3)]2}2 and [Bi(S2CNBu2)2(CH3OH)(NO3)]∞[J].Chinese Journal of Chemistry,2005,23(12):1631-1636. |
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| Authors: | YIN Han-Dong WANG Chuan-Hua XING Qiu-Ju |
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| Institution: | Department of Chemistry, Liaocheng University, Liaocheng, Shandong 252059, China |
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| Abstract: | Three bismuth(III) complexes Bi(1,10‐phen)S2CN(CH3)2]2(NO3) ( 1 ), {Bi(S2COCH3)S2CNC6H5(CH3)]2}2 ( 2 ) and Bi(S2CNBu2)2(CH3OH)(NO3)]∞ ( 3 ) were synthesized and characterized by elemental analysis and IR spectra. Their crystal structures were determined by X‐ray single crystal diffraction analysis. Studies show that complex 1 has a monomeric structure with the central bismuth atom eight‐coordinated in a capped distorted pentagonal bipyramidal geometry. The complex 2 takes centrosymmetric dimeric structure and the bismuth atoms are seven‐coordinated in distorted pentagonal bipyramidal geometry. In complex 3 , the bismuth atoms are seven‐coordinated in distorted pentagonal bipyramidal geometry by bridging nitrate O atoms and the resulting structure is one‐dimensional infinite chain polymer. |
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| Keywords: | bismuth(III) complex dithiocarbamate xanthate crystal structure |
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