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Synthesis, Characterization and Crystal Structure of (Z)-1-[2-(Triarylstannyl)vinyl]-1-indanols and Their Arylhalostannyl Derivatives
引用本文:朱东升,吕春胜,梅泽民,高伟,张越涛,母瀛,王宗睦.Synthesis, Characterization and Crystal Structure of (Z)-1-[2-(Triarylstannyl)vinyl]-1-indanols and Their Arylhalostannyl Derivatives[J].中国化学,2004,22(4):348-353.
作者姓名:朱东升  吕春胜  梅泽民  高伟  张越涛  母瀛  王宗睦
作者单位:SchoolofChemistry,JilinUniversity,Changchun,Jilin130023,China
基金项目:theNationalNaturalScienceFoundationofChina(Nos.29734143,29672013).
摘    要:(Z)-1-2-(Tri-o-tolylstannyl)vinyl]-1-indanol (1) and (Z)-1-2-(tri-p-tolylstannyl)vinyl]-l-indanol (2) were synthesized by the addition reaction of 1-ethynylindanol with tri-o-tolyltin and tri-p-tolyltin hydride. The aryl groups in compound 1 and 2 were substituted by Br2 or I2 to yield monohalide derivatives (3-6). The compounds 1-6 were characterized by elemental analysis, ^1H NMR and FT-IR spectroscopy. The crystal structures of 1, 2 and 4 have been determined by single crystal X-ray diffraction analysis. The Sn atom in 1 and 2 exhibits a tetrahedral geometry distorted towards trigonal bipyramid due to a weak intramolecular interaction between Sn and the hydroxyl O atoms 0.2839(4) nm and 0.2744(5) nm], while the Sn atom in 4 adopts a trigonal bipyramidal geometry with a significant O→Sn(1) interaction 0.2552(5) nm].

关 键 词:有机锡化合物  (Z)-1-[2(三苯基甲锡烷基)乙烯基]-1-茚醇  FT—IR光谱学  NMR光谱学  X射线晶体结构

Synthesis, Characterization and Crystal Structure of (Z)-1-[2-(Triarylstannyl)vinyl]-1-indanols and Their Arylha-lostannyl Derivatives
ZHU,Dong-Shenga,b LV Chun-Shenga MEI,Ze-MinaGAO,Weia ZHANG,Yue-Taoa MU,Ying,a WANG,Zong-Mua a School of Chemistry,Jilin University,Changchun,Jilin ,China b School of Chemistry,Northeast Normal University,Changchun,Jilin ,China.Synthesis, Characterization and Crystal Structure of (Z)-1-[2-(Triarylstannyl)vinyl]-1-indanols and Their Arylha-lostannyl Derivatives[J].Chinese Journal of Chemistry,2004,22(4):348-353.
Authors:ZHU  Dong-Shenga  b LV Chun-Shenga MEI  Ze-MinaGAO  Weia ZHANG  Yue-Taoa MU  Ying  a WANG  Zong-Mua a School of Chemistry  Jilin University  Changchun  Jilin  China b School of Chemistry  Northeast Normal University  Changchun  Jilin  China
Institution:ZHU,Dong-Shenga,b LV Chun-Shenga MEI,Ze-MinaGAO,Weia ZHANG,Yue-Taoa MU,Ying*,a WANG,Zong-Mua a School of Chemistry,Jilin University,Changchun,Jilin 130023,China b School of Chemistry,Northeast Normal University,Changchun,Jilin 130024,China
Abstract:(Z)‐1‐2‐(Tri‐o‐tolylstannyl)vinyl]‐l‐indanol(1) and (Z)‐1‐2‐(tri‐p‐tolylstannyl)vinyl]‐l‐indanol (2) were synthesized by the addition reaction of l‐ethynylindanol with tri‐o‐tolyltin and m‐p‐tolyltin hydride. The aryl groups in compound 1 and 2 were substituted by Br2 or I2 to yield monohalide derivatives (3–6). The compounds 1–6 were characterized by elemental analysis, 1H NMR and FT‐IR spectroscopy. The crystal structures of 1, 2 and 4 have been determined by single crystal X‐ray diffraction analysis. The Sn atom in 1 and 2 exhibits a tetrahedral geometry distorted towards trigonal bipyramid due to a weak intramolecular interaction between Sn and the hydroxyl O atoms 02839(4) nm and 0.2744(5) nm], while the Sn atom in 4 adopts a trigonal bipyramidal geometry with a significant 0→Sn(1) interaction 0.2552(5) nm].
Keywords:organotin compounds  aryltin compounds  FT-IR spectroscopy  NMR spectroscopy  X-ray crystal structure
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